Spectrophotometric determination of association constant: Computer program STEP

Jens Spanget-Larsen

doi:10.13140/RG.2.1.3388.7765

Spectrophotometric determination of association constant: Computer program STEP

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Abstract

Least-squares 'Systematic Trial-and-Error Procedure' (STEP) for spectrophotometric evaluation of association constant (equilibrium constant) K and molar absorption coefficient E for a 1:1 molecular complex, A + B = C, with error analysis according to Conrow et al. (1964). An analysis of the Charge Transfer (CT) complex formation of naphthalene and chloranil is provided as an example.

Original language	English
Publication date	3 Feb 2016
DOIs	https://doi.org/10.13140/RG.2.1.3388.7765
Publication status	Published - 3 Feb 2016

Keywords

Spectrophotometry
Association constant
Equilibrium constant
Lambert-Beer's "law"
Charge Transfer (CT) complex

Link to document

10.13140/RG.2.1.3388.7765Licence: Unspecified

STEP2016Final published version, 445 KB

Cite this

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title = "Spectrophotometric determination of association constant: Computer program STEP",

abstract = "Least-squares 'Systematic Trial-and-Error Procedure' (STEP) for spectrophotometric evaluation of association constant (equilibrium constant) K and molar absorption coefficient E for a 1:1 molecular complex, A + B = C, with error analysis according to Conrow et al. (1964). An analysis of the Charge Transfer (CT) complex formation of naphthalene and chloranil is provided as an example.",

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