Abstract
Least-squares 'Systematic Trial-and-Error Procedure' (STEP) for spectrophotometric evaluation of association constant (equilibrium constant) K and molar absorption coefficient E for a 1:1 molecular complex, A + B = C, with error analysis according to Conrow et al. (1964). An analysis of the Charge Transfer (CT) complex formation of naphthalene and chloranil is provided as an example.
Original language | English |
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Publication date | 3 Feb 2016 |
DOIs | |
Publication status | Published - 3 Feb 2016 |
Keywords
- Spectrophotometry
- Association constant
- Equilibrium constant
- Lambert-Beer's "law"
- Charge Transfer (CT) complex