Solid state tautomerism in 2-((phenylimino)methyl)naphthalene-1-ol

Daniela Nedeltcheva, Fadhil S. Kamounah, Laurent Mirolo, Katharina M. Fromm, Liudmil Antonov

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    The solid state tautomerism of 2-((phenylimino)methyl)naphthalene-1-ol was studied using X-ray measurements and absorption spectroscopy. In the solid state, the keto tautomer predominates. The observed shift in the equilibrium from the enol (dilute solution) to the keto (solid state) forms is explained by the formation of dye aggregates using ab initio quantum chemical calculations
    Original languageEnglish
    JournalDyes and Pigments
    Volume83
    Issue number1
    Pages (from-to)121-126
    ISSN0143-7208
    Publication statusPublished - 2009

    Keywords

    • Tautomerism
    • Schiff bases
    • Intramolecular proton transfer
    • Crystallography
    • Spectroscopy
    • Photochromic dyes

    Cite this

    Nedeltcheva, D., Kamounah, F. S., Mirolo, L., Fromm, K. M., & Antonov, L. (2009). Solid state tautomerism in 2-((phenylimino)methyl)naphthalene-1-ol. Dyes and Pigments, 83(1), 121-126.