Generalized single-parameter aging tests and their application to glycerol

Lisa Anita Roed; Tina Hecksher; Jeppe Dyre; Kristine Niss

doi:10.1063/1.5066387

Generalized single-parameter aging tests and their application to glycerol

Lisa Anita Roed, Tina Hecksher, Jeppe Dyre, Kristine Niss

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Physical aging of glycerol following temperature jumps is studied by dielectric spectroscopy at temperatures just below the glass transition temperature. The data are analyzed using two single-parameter aging tests developed by Hecksher et al. [J. Chem. Phys. 142, 241103 (2015)]. We generalize these tests to include jumps ending at different temperatures. Moreover, four times larger jumps than previously are studied. The single-parameter aging tests are here for the first time applied to a hydrogen-bonded liquid. We conclude that glycerol obeys single-parameter aging to a good approximation.

Original language	English
Article number	044501
Journal	The Journal of Chemical Physics
Volume	150
Issue number	4
Number of pages	8
ISSN	0021-9606
DOIs	https://doi.org/10.1063/1.5066387
Publication status	Published - 23 Jan 2019

Keywords

Viscous liquid
Glass transitions
Isomorph theory
Organic compounds
Dielectric properties
Dielectric spectroscopy
Hydrogen bonding
Aging theory

Cite this

Roed, L. A., Hecksher, T., Dyre, J., & Niss, K. (2019). Generalized single-parameter aging tests and their application to glycerol. The Journal of Chemical Physics, 150(4), [044501]. https://doi.org/10.1063/1.5066387

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title = "Generalized single-parameter aging tests and their application to glycerol",

abstract = "Physical aging of glycerol following temperature jumps is studied by dielectric spectroscopy at temperatures just below the glass transition temperature. The data are analyzed using two single-parameter aging tests developed by Hecksher et al. [J. Chem. Phys. 142, 241103 (2015)]. We generalize these tests to include jumps ending at different temperatures. Moreover, four times larger jumps than previously are studied. The single-parameter aging tests are here for the first time applied to a hydrogen-bonded liquid. We conclude that glycerol obeys single-parameter aging to a good approximation.",

keywords = "Viscous liquid, Glass transitions, Isomorph theory, Organic compounds, Dielectric properties, Dielectric spectroscopy, Hydrogen bonding, Aging theory",

author = "Roed, {Lisa Anita} and Tina Hecksher and Jeppe Dyre and Kristine Niss",

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AU - Roed, Lisa Anita

AU - Hecksher, Tina

AU - Dyre, Jeppe

AU - Niss, Kristine

PY - 2019/1/23

Y1 - 2019/1/23

N2 - Physical aging of glycerol following temperature jumps is studied by dielectric spectroscopy at temperatures just below the glass transition temperature. The data are analyzed using two single-parameter aging tests developed by Hecksher et al. [J. Chem. Phys. 142, 241103 (2015)]. We generalize these tests to include jumps ending at different temperatures. Moreover, four times larger jumps than previously are studied. The single-parameter aging tests are here for the first time applied to a hydrogen-bonded liquid. We conclude that glycerol obeys single-parameter aging to a good approximation.

AB - Physical aging of glycerol following temperature jumps is studied by dielectric spectroscopy at temperatures just below the glass transition temperature. The data are analyzed using two single-parameter aging tests developed by Hecksher et al. [J. Chem. Phys. 142, 241103 (2015)]. We generalize these tests to include jumps ending at different temperatures. Moreover, four times larger jumps than previously are studied. The single-parameter aging tests are here for the first time applied to a hydrogen-bonded liquid. We conclude that glycerol obeys single-parameter aging to a good approximation.

KW - Viscous liquid

KW - Glass transitions

KW - Isomorph theory

KW - Organic compounds

KW - Dielectric properties

KW - Dielectric spectroscopy

KW - Hydrogen bonding

KW - Aging theory

U2 - 10.1063/1.5066387

DO - 10.1063/1.5066387

M3 - Journal article

VL - 150

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 4

M1 - 044501

ER -

Link to document

10.1063/1.5066387

Generalized single-parameter aging tests and their application toglycerolSubmitted manuscript, 545 KB