Abstract
The temperature dependence of the high-frequency shear modulus measured in the kHz range is compared with the mean-squared displacement measured in the nanosecond range for the two van der Waals bonded glass-forming liquids cumene and 5-polyphenyl ether. This provides an experimental test for the assumption
connecting two versions of the shoving model for the non-Arrhenius temperature dependence of the relaxation time in glass formers. The two versions of the model are also tested directly and both are shown to work well for these liquids.
connecting two versions of the shoving model for the non-Arrhenius temperature dependence of the relaxation time in glass formers. The two versions of the model are also tested directly and both are shown to work well for these liquids.
Original language | English |
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Article number | 104202 |
Journal | Physical Review B (Condensed Matter and Materials Physics) |
Volume | 95 |
Issue number | 10 |
ISSN | 1098-0121 |
DOIs | |
Publication status | Published - 10 Mar 2017 |
Keywords
- Viscoelasticity
- Glass transition
- Liquids
- Rheology techniques
- Neutron scattering