Connection between fragility, mean-squared displacement and shear modulus in two van der Waals bonded glass-forming liquids

Henriette Wase Hansen, Bernhard Frick, Tina Hecksher, Jeppe C. Dyre, Kristine Niss

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

The temperature dependence of the high-frequency shear modulus measured in the kHz range is compared with the mean-squared displacement measured in the nanosecond range for the two van der Waals bonded glass-forming liquids cumene and 5-polyphenyl ether. This provides an experimental test for the assumption
connecting two versions of the shoving model for the non-Arrhenius temperature dependence of the relaxation time in glass formers. The two versions of the model are also tested directly and both are shown to work well for these liquids.
Original languageEnglish
Article number104202
JournalPhysical Review B (Condensed Matter and Materials Physics)
Volume95
Issue number10
ISSN1098-0121
DOIs
Publication statusPublished - 10 Mar 2017

Keywords

  • Viscoelasticity
  • Glass transition
  • Liquids
  • Rheology techniques
  • Neutron scattering

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