40Ar/39Ar dating of Quaternary volcanic ashes by multi-collection noble gas mass spectrometry: protocols, precision and intercalibration

Michael Storey, Tiffany Rivera, Stephanie Flude, Ole Stecher

    Research output: Contribution to conferenceConference abstract for conferenceResearch

    Abstract

    The recent availability of commercial high-resolution, multi-collector, noble gas mass spectrometers equipped with ion-counting electron multipliers provides new opportunities for improved precision in 40Ar/39Ar dating. This is particularly true for single crystal dating of Quaternary aged samples where potassium-bearing phenocrysts may contain relatively small amounts of radiogenic 40Ar.

    In 2005, the Quaternary Dating Laboratory, Roskilde University, installed a Nu-Instruments multi-collector Noblesse noble gas mass spectrometer, which is configured with a Faraday detector and three ion-counting electron multipliers. The instrument has the capability to measure several isotopes simultaneously and to change measurement configurations instantaneously by the use of QUAD lenses (zoom optics). The Noblesse offers several advantages over previous generation instruments and is particularly suited for single crystal 40Ar/39Ar dating of Quaternary samples because of: (i) improved source sensitivity; (ii) ion-counting electron multipliers, which have low signal to noise ratios enabling precise measurement of very small 36Ar signals - resulting in accurate correction for atmospheric-derived 40Ar; (iii) higher mass resolution allows hydrocarbon interferences to be pseudo resolved for the different argon isotopes; and (iv) multi-collection, allowing more data to be gathered in a fixed time in comparison with single-collector peak-switching measurements.

    We evaluate (i) protocols for detector inter-calibration and instrument mass fractionation using argon from a calibrated air pipette; (ii) precision and long-term data reproducibility; and (iii) results from inter-calibration experiments of 40Ar/39Ar ages on Quaternary volcanic ashes with the U-Pb, astronomical and historical chronometers.
    Original languageEnglish
    Publication dateJul 2011
    Publication statusPublished - Jul 2011
    EventXVIII INQUA Congress - Bern, Switzerland
    Duration: 21 Jul 201127 Jul 2011
    Conference number: 18
    http://www.inqua2011.ch/

    Conference

    ConferenceXVIII INQUA Congress
    Number18
    CountrySwitzerland
    CityBern
    Period21/07/201127/07/2011
    Internet address

    Cite this

    Storey, M., Rivera, T., Flude, S., & Stecher, O. (2011). 40Ar/39Ar dating of Quaternary volcanic ashes by multi-collection noble gas mass spectrometry: protocols, precision and intercalibration. Abstract from XVIII INQUA Congress, Bern, Switzerland.
    Storey, Michael ; Rivera, Tiffany ; Flude, Stephanie ; Stecher, Ole. / 40Ar/39Ar dating of Quaternary volcanic ashes by multi-collection noble gas mass spectrometry: protocols, precision and intercalibration. Abstract from XVIII INQUA Congress, Bern, Switzerland.
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    abstract = "The recent availability of commercial high-resolution, multi-collector, noble gas mass spectrometers equipped with ion-counting electron multipliers provides new opportunities for improved precision in 40Ar/39Ar dating. This is particularly true for single crystal dating of Quaternary aged samples where potassium-bearing phenocrysts may contain relatively small amounts of radiogenic 40Ar. In 2005, the Quaternary Dating Laboratory, Roskilde University, installed a Nu-Instruments multi-collector Noblesse noble gas mass spectrometer, which is configured with a Faraday detector and three ion-counting electron multipliers. The instrument has the capability to measure several isotopes simultaneously and to change measurement configurations instantaneously by the use of QUAD lenses (zoom optics). The Noblesse offers several advantages over previous generation instruments and is particularly suited for single crystal 40Ar/39Ar dating of Quaternary samples because of: (i) improved source sensitivity; (ii) ion-counting electron multipliers, which have low signal to noise ratios enabling precise measurement of very small 36Ar signals - resulting in accurate correction for atmospheric-derived 40Ar; (iii) higher mass resolution allows hydrocarbon interferences to be pseudo resolved for the different argon isotopes; and (iv) multi-collection, allowing more data to be gathered in a fixed time in comparison with single-collector peak-switching measurements.We evaluate (i) protocols for detector inter-calibration and instrument mass fractionation using argon from a calibrated air pipette; (ii) precision and long-term data reproducibility; and (iii) results from inter-calibration experiments of 40Ar/39Ar ages on Quaternary volcanic ashes with the U-Pb, astronomical and historical chronometers.",
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    language = "English",
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    Storey, M, Rivera, T, Flude, S & Stecher, O 2011, '40Ar/39Ar dating of Quaternary volcanic ashes by multi-collection noble gas mass spectrometry: protocols, precision and intercalibration' XVIII INQUA Congress, Bern, Switzerland, 21/07/2011 - 27/07/2011, .

    40Ar/39Ar dating of Quaternary volcanic ashes by multi-collection noble gas mass spectrometry: protocols, precision and intercalibration. / Storey, Michael; Rivera, Tiffany; Flude, Stephanie; Stecher, Ole.

    2011. Abstract from XVIII INQUA Congress, Bern, Switzerland.

    Research output: Contribution to conferenceConference abstract for conferenceResearch

    TY - ABST

    T1 - 40Ar/39Ar dating of Quaternary volcanic ashes by multi-collection noble gas mass spectrometry: protocols, precision and intercalibration

    AU - Storey, Michael

    AU - Rivera, Tiffany

    AU - Flude, Stephanie

    AU - Stecher, Ole

    PY - 2011/7

    Y1 - 2011/7

    N2 - The recent availability of commercial high-resolution, multi-collector, noble gas mass spectrometers equipped with ion-counting electron multipliers provides new opportunities for improved precision in 40Ar/39Ar dating. This is particularly true for single crystal dating of Quaternary aged samples where potassium-bearing phenocrysts may contain relatively small amounts of radiogenic 40Ar. In 2005, the Quaternary Dating Laboratory, Roskilde University, installed a Nu-Instruments multi-collector Noblesse noble gas mass spectrometer, which is configured with a Faraday detector and three ion-counting electron multipliers. The instrument has the capability to measure several isotopes simultaneously and to change measurement configurations instantaneously by the use of QUAD lenses (zoom optics). The Noblesse offers several advantages over previous generation instruments and is particularly suited for single crystal 40Ar/39Ar dating of Quaternary samples because of: (i) improved source sensitivity; (ii) ion-counting electron multipliers, which have low signal to noise ratios enabling precise measurement of very small 36Ar signals - resulting in accurate correction for atmospheric-derived 40Ar; (iii) higher mass resolution allows hydrocarbon interferences to be pseudo resolved for the different argon isotopes; and (iv) multi-collection, allowing more data to be gathered in a fixed time in comparison with single-collector peak-switching measurements.We evaluate (i) protocols for detector inter-calibration and instrument mass fractionation using argon from a calibrated air pipette; (ii) precision and long-term data reproducibility; and (iii) results from inter-calibration experiments of 40Ar/39Ar ages on Quaternary volcanic ashes with the U-Pb, astronomical and historical chronometers.

    AB - The recent availability of commercial high-resolution, multi-collector, noble gas mass spectrometers equipped with ion-counting electron multipliers provides new opportunities for improved precision in 40Ar/39Ar dating. This is particularly true for single crystal dating of Quaternary aged samples where potassium-bearing phenocrysts may contain relatively small amounts of radiogenic 40Ar. In 2005, the Quaternary Dating Laboratory, Roskilde University, installed a Nu-Instruments multi-collector Noblesse noble gas mass spectrometer, which is configured with a Faraday detector and three ion-counting electron multipliers. The instrument has the capability to measure several isotopes simultaneously and to change measurement configurations instantaneously by the use of QUAD lenses (zoom optics). The Noblesse offers several advantages over previous generation instruments and is particularly suited for single crystal 40Ar/39Ar dating of Quaternary samples because of: (i) improved source sensitivity; (ii) ion-counting electron multipliers, which have low signal to noise ratios enabling precise measurement of very small 36Ar signals - resulting in accurate correction for atmospheric-derived 40Ar; (iii) higher mass resolution allows hydrocarbon interferences to be pseudo resolved for the different argon isotopes; and (iv) multi-collection, allowing more data to be gathered in a fixed time in comparison with single-collector peak-switching measurements.We evaluate (i) protocols for detector inter-calibration and instrument mass fractionation using argon from a calibrated air pipette; (ii) precision and long-term data reproducibility; and (iii) results from inter-calibration experiments of 40Ar/39Ar ages on Quaternary volcanic ashes with the U-Pb, astronomical and historical chronometers.

    M3 - Conference abstract for conference

    ER -

    Storey M, Rivera T, Flude S, Stecher O. 40Ar/39Ar dating of Quaternary volcanic ashes by multi-collection noble gas mass spectrometry: protocols, precision and intercalibration. 2011. Abstract from XVIII INQUA Congress, Bern, Switzerland.