Resumé
| Originalsprog | Engelsk |
|---|---|
| Tidsskrift | ChemCatChem |
| Vol/bind | 7 |
| Udgave nummer | 6 |
| Sider (fra-til) | 1023-1028 |
| Antal sider | 6 |
| ISSN | 1867-3880 |
| DOI | |
| Status | Udgivet - 2015 |
| Udgivet eksternt | Ja |
Citer dette
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Tuneable Hydrogenation of Nitriles into Imines or Amines with a Ruthenium Pincer Complex under Mild Conditions. / Choi, Jong-Hoo; Prechtl, Martin H. G.
I: ChemCatChem, Bind 7, Nr. 6, 2015, s. 1023-1028.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review
TY - JOUR
T1 - Tuneable Hydrogenation of Nitriles into Imines or Amines with a Ruthenium Pincer Complex under Mild Conditions
AU - Choi, Jong-Hoo
AU - Prechtl, Martin H. G.
PY - 2015
Y1 - 2015
N2 - The selective hydrogenation of aromatic and aliphatic nitriles into amines and imines is described. Using a ruthenium pincer complex, the selectivity towards amines or imines can be controlled by simple parameter changes. The reactions are conducted under very mild conditions between 50-100 degrees C at 0.4MPa H-2 pressure without any additives at low catalytic loadings of 0.5-1mol%, which results in quantitative conversions and high selectivity.
AB - The selective hydrogenation of aromatic and aliphatic nitriles into amines and imines is described. Using a ruthenium pincer complex, the selectivity towards amines or imines can be controlled by simple parameter changes. The reactions are conducted under very mild conditions between 50-100 degrees C at 0.4MPa H-2 pressure without any additives at low catalytic loadings of 0.5-1mol%, which results in quantitative conversions and high selectivity.
U2 - 10.1002/cctc.201403047
DO - 10.1002/cctc.201403047
M3 - Journal article
VL - 7
SP - 1023
EP - 1028
JO - ChemCatChem
JF - ChemCatChem
SN - 1867-3880
IS - 6
ER -