Tuneable Hydrogenation of Nitriles into Imines or Amines with a Ruthenium Pincer Complex under Mild Conditions

Jong-Hoo Choi, Martin H. G. Prechtl

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

Resumé

The selective hydrogenation of aromatic and aliphatic nitriles into amines and imines is described. Using a ruthenium pincer complex, the selectivity towards amines or imines can be controlled by simple parameter changes. The reactions are conducted under very mild conditions between 50-100 degrees C at 0.4MPa H-2 pressure without any additives at low catalytic loadings of 0.5-1mol%, which results in quantitative conversions and high selectivity.
OriginalsprogEngelsk
TidsskriftChemCatChem
Vol/bind7
Udgave nummer6
Sider (fra-til)1023-1028
Antal sider6
ISSN1867-3880
DOI
StatusUdgivet - 2015
Udgivet eksterntJa

Citer dette

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abstract = "The selective hydrogenation of aromatic and aliphatic nitriles into amines and imines is described. Using a ruthenium pincer complex, the selectivity towards amines or imines can be controlled by simple parameter changes. The reactions are conducted under very mild conditions between 50-100 degrees C at 0.4MPa H-2 pressure without any additives at low catalytic loadings of 0.5-1mol{\%}, which results in quantitative conversions and high selectivity.",
author = "Jong-Hoo Choi and Prechtl, {Martin H. G.}",
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Tuneable Hydrogenation of Nitriles into Imines or Amines with a Ruthenium Pincer Complex under Mild Conditions. / Choi, Jong-Hoo; Prechtl, Martin H. G.

I: ChemCatChem, Bind 7, Nr. 6, 2015, s. 1023-1028.

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

TY - JOUR

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AU - Choi, Jong-Hoo

AU - Prechtl, Martin H. G.

PY - 2015

Y1 - 2015

N2 - The selective hydrogenation of aromatic and aliphatic nitriles into amines and imines is described. Using a ruthenium pincer complex, the selectivity towards amines or imines can be controlled by simple parameter changes. The reactions are conducted under very mild conditions between 50-100 degrees C at 0.4MPa H-2 pressure without any additives at low catalytic loadings of 0.5-1mol%, which results in quantitative conversions and high selectivity.

AB - The selective hydrogenation of aromatic and aliphatic nitriles into amines and imines is described. Using a ruthenium pincer complex, the selectivity towards amines or imines can be controlled by simple parameter changes. The reactions are conducted under very mild conditions between 50-100 degrees C at 0.4MPa H-2 pressure without any additives at low catalytic loadings of 0.5-1mol%, which results in quantitative conversions and high selectivity.

U2 - 10.1002/cctc.201403047

DO - 10.1002/cctc.201403047

M3 - Journal article

VL - 7

SP - 1023

EP - 1028

JO - ChemCatChem

JF - ChemCatChem

SN - 1867-3880

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ER -