Thiocyanate ligand substitution kinetics of the solar cell dye Z-907 by 3-methoxypropionitrile and 4-tert-butylpyridine at elevated temperatures

Nguyen Tuyet Phuong, Rikke Degn, Thai Hoang Nguyen, Torben Lund

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

Resumé

The dye sensitized solar cell dye Z-907, [RuLL´(NCS)2] may loose a thiocyanate ligand at elevated temperatures (80-100 ºC) by ligand exchange with the solar cell additive 4-tert-butylpyridine

(4-TBP) or the electrolyte solvent 3-methoxypropionitrile (3-MPN). The mechanism in homogeneous solution proceeds via three equilibrium reactions (eqs. 1-3) with the solvent complex [RuLL´(NCS)(3-MPN)] as an intermediate:

 

[RuLL´(NCS)2] + 3-MPN = [RuLL´(NCS)(3-MPN)]+ + NCS- (1)

[RuLL´(NCS)(3-MPN)]+ + 4-TBP = [RuLL´(NCS)(4-TBP)]+ + 3-MPN (2)


[RuLL´(NCS)2] + 4-TBP = [RuLL´(NCS)(4-TBP)]+ + NCS- (3)

 

 

A similar mechanism describes the heterogeneous substitution reactions of Z-907 attached to the surface of TiO2 particles with 3-MPN and 4-TBP. All the six homogeneous and heterogeneous rate constants were obtained at 100 ºC by monitoring the decay of Z-907 and product formation in test tube experiments by HPLC coupled to UV/Vis and electrospray mass spectrometry.

A half life time t1/2 = 150 h was obtained for the Z-907 dye bound to TiO2 nano crystalline particles at 85 ºC in presence of 4-TBP and 3-MPN. Dye sensitized solar cells (DSC) with Z-907 as sensitizer and application of the so called “non robust” electrolytes containing 4-TBP and 3-MPN is therefore not expected to be able to pass a 1000 h thermal stress test at 85 ºC. Addition of thiocyanate to the cell electrolyte may however, eliminate or reduce the problems caused by dye thiocyanate ligand substitution in DSC cells.

OriginalsprogEngelsk
TidsskriftSolar Energy Materials & Solar Cells
Vol/bind93
Udgave nummer11
Sider (fra-til)1939-1945
Antal sider7
ISSN0927-0248
DOI
StatusUdgivet - 2009

Emneord

  • Farvestof solcelle
  • ruthenium farvestofkemi

Citer dette

@article{10904e20060511df9853000ea68e967b,
title = "Thiocyanate ligand substitution kinetics of the solar cell dye Z-907 by 3-methoxypropionitrile and 4-tert-butylpyridine at elevated temperatures",
abstract = "The dye sensitized solar cell dye Z-907, [RuLL´(NCS)2] may loose a thiocyanate ligand at elevated temperatures (80-100 ºC) by ligand exchange with the solar cell additive 4-tert-butylpyridine (4-TBP) or the electrolyte solvent 3-methoxypropionitrile (3-MPN). The mechanism in homogeneous solution proceeds via three equilibrium reactions (eqs. 1-3) with the solvent complex [RuLL´(NCS)(3-MPN)] as an intermediate: [RuLL´(NCS)2] + 3-MPN = [RuLL´(NCS)(3-MPN)]+ + NCS- (1)[RuLL´(NCS)(3-MPN)]+ + 4-TBP = [RuLL´(NCS)(4-TBP)]+ + 3-MPN (2)[RuLL´(NCS)2] + 4-TBP = [RuLL´(NCS)(4-TBP)]+ + NCS- (3)  A similar mechanism describes the heterogeneous substitution reactions of Z-907 attached to the surface of TiO2 particles with 3-MPN and 4-TBP. All the six homogeneous and heterogeneous rate constants were obtained at 100 ºC by monitoring the decay of Z-907 and product formation in test tube experiments by HPLC coupled to UV/Vis and electrospray mass spectrometry. A half life time t1/2 = 150 h was obtained for the Z-907 dye bound to TiO2 nano crystalline particles at 85 ºC in presence of 4-TBP and 3-MPN. Dye sensitized solar cells (DSC) with Z-907 as sensitizer and application of the so called “non robust” electrolytes containing 4-TBP and 3-MPN is therefore not expected to be able to pass a 1000 h thermal stress test at 85 ºC. Addition of thiocyanate to the cell electrolyte may however, eliminate or reduce the problems caused by dye thiocyanate ligand substitution in DSC cells.",
keywords = "Farvestof solcelle, ruthenium farvestofkemi, Z-907, Thermal stability, Thiocyanate substitution, LC-MS",
author = "Phuong, {Nguyen Tuyet} and Rikke Degn and Nguyen, {Thai Hoang} and Torben Lund",
year = "2009",
doi = "10.1016/j.solmat.2009.07.008",
language = "English",
volume = "93",
pages = "1939--1945",
journal = "Solar Energy Materials & Solar Cells",
issn = "0927-0248",
publisher = "Elsevier BV * North-Holland",
number = "11",

}

Thiocyanate ligand substitution kinetics of the solar cell dye Z-907 by 3-methoxypropionitrile and 4-tert-butylpyridine at elevated temperatures. / Phuong, Nguyen Tuyet; Degn, Rikke; Nguyen, Thai Hoang; Lund, Torben.

I: Solar Energy Materials & Solar Cells, Bind 93, Nr. 11, 2009, s. 1939-1945.

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

TY - JOUR

T1 - Thiocyanate ligand substitution kinetics of the solar cell dye Z-907 by 3-methoxypropionitrile and 4-tert-butylpyridine at elevated temperatures

AU - Phuong, Nguyen Tuyet

AU - Degn, Rikke

AU - Nguyen, Thai Hoang

AU - Lund, Torben

PY - 2009

Y1 - 2009

N2 - The dye sensitized solar cell dye Z-907, [RuLL´(NCS)2] may loose a thiocyanate ligand at elevated temperatures (80-100 ºC) by ligand exchange with the solar cell additive 4-tert-butylpyridine (4-TBP) or the electrolyte solvent 3-methoxypropionitrile (3-MPN). The mechanism in homogeneous solution proceeds via three equilibrium reactions (eqs. 1-3) with the solvent complex [RuLL´(NCS)(3-MPN)] as an intermediate: [RuLL´(NCS)2] + 3-MPN = [RuLL´(NCS)(3-MPN)]+ + NCS- (1)[RuLL´(NCS)(3-MPN)]+ + 4-TBP = [RuLL´(NCS)(4-TBP)]+ + 3-MPN (2)[RuLL´(NCS)2] + 4-TBP = [RuLL´(NCS)(4-TBP)]+ + NCS- (3)  A similar mechanism describes the heterogeneous substitution reactions of Z-907 attached to the surface of TiO2 particles with 3-MPN and 4-TBP. All the six homogeneous and heterogeneous rate constants were obtained at 100 ºC by monitoring the decay of Z-907 and product formation in test tube experiments by HPLC coupled to UV/Vis and electrospray mass spectrometry. A half life time t1/2 = 150 h was obtained for the Z-907 dye bound to TiO2 nano crystalline particles at 85 ºC in presence of 4-TBP and 3-MPN. Dye sensitized solar cells (DSC) with Z-907 as sensitizer and application of the so called “non robust” electrolytes containing 4-TBP and 3-MPN is therefore not expected to be able to pass a 1000 h thermal stress test at 85 ºC. Addition of thiocyanate to the cell electrolyte may however, eliminate or reduce the problems caused by dye thiocyanate ligand substitution in DSC cells.

AB - The dye sensitized solar cell dye Z-907, [RuLL´(NCS)2] may loose a thiocyanate ligand at elevated temperatures (80-100 ºC) by ligand exchange with the solar cell additive 4-tert-butylpyridine (4-TBP) or the electrolyte solvent 3-methoxypropionitrile (3-MPN). The mechanism in homogeneous solution proceeds via three equilibrium reactions (eqs. 1-3) with the solvent complex [RuLL´(NCS)(3-MPN)] as an intermediate: [RuLL´(NCS)2] + 3-MPN = [RuLL´(NCS)(3-MPN)]+ + NCS- (1)[RuLL´(NCS)(3-MPN)]+ + 4-TBP = [RuLL´(NCS)(4-TBP)]+ + 3-MPN (2)[RuLL´(NCS)2] + 4-TBP = [RuLL´(NCS)(4-TBP)]+ + NCS- (3)  A similar mechanism describes the heterogeneous substitution reactions of Z-907 attached to the surface of TiO2 particles with 3-MPN and 4-TBP. All the six homogeneous and heterogeneous rate constants were obtained at 100 ºC by monitoring the decay of Z-907 and product formation in test tube experiments by HPLC coupled to UV/Vis and electrospray mass spectrometry. A half life time t1/2 = 150 h was obtained for the Z-907 dye bound to TiO2 nano crystalline particles at 85 ºC in presence of 4-TBP and 3-MPN. Dye sensitized solar cells (DSC) with Z-907 as sensitizer and application of the so called “non robust” electrolytes containing 4-TBP and 3-MPN is therefore not expected to be able to pass a 1000 h thermal stress test at 85 ºC. Addition of thiocyanate to the cell electrolyte may however, eliminate or reduce the problems caused by dye thiocyanate ligand substitution in DSC cells.

KW - Farvestof solcelle

KW - ruthenium farvestofkemi

KW - Z-907

KW - Thermal stability

KW - Thiocyanate substitution

KW - LC-MS

U2 - 10.1016/j.solmat.2009.07.008

DO - 10.1016/j.solmat.2009.07.008

M3 - Journal article

VL - 93

SP - 1939

EP - 1945

JO - Solar Energy Materials & Solar Cells

JF - Solar Energy Materials & Solar Cells

SN - 0927-0248

IS - 11

ER -