The Role of Ionic Liquids in Hydrogen Storage

Sebastian Sahler; Sebastian Sturm; Michael T. Kessler; Martin H. G. Prechtl

doi:10.1002/chem.201304868

The Role of Ionic Liquids in Hydrogen Storage

Sebastian Sahler, Sebastian Sturm, Michael T. Kessler, Martin H. G. Prechtl

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Abstract

Ionic liquid (IL) based H-2 storage for H-2 generation from NH3BH3 derivatives is shown. These systems promote H-2 generation at low temperature, with good reaction rates and high total H-2 yields. The effects of ILs and the H-2 yield in correlation with the basicity, the cations of the ILs, and the role of carbenes are discussed. Furthermore, mechanistic findings on the dehydrogenation are described. IL material blends are competitive with conventional H-2 storage materials with experimental efficiencies of at least 6.5 wt% H-2.

Originalsprog	Engelsk
Tidsskrift	Chemistry: A European Journal
Vol/bind	20
Udgave nummer	29
Sider (fra-til)	8934-8941
Antal sider	8
ISSN	0947-6539
DOI	https://doi.org/10.1002/chem.201304868
Status	Udgivet - 2014
Udgivet eksternt	Ja

Link til dokument

10.1002/chem.201304868

Citer dette

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AB - Ionic liquid (IL) based H-2 storage for H-2 generation from NH3BH3 derivatives is shown. These systems promote H-2 generation at low temperature, with good reaction rates and high total H-2 yields. The effects of ILs and the H-2 yield in correlation with the basicity, the cations of the ILs, and the role of carbenes are discussed. Furthermore, mechanistic findings on the dehydrogenation are described. IL material blends are competitive with conventional H-2 storage materials with experimental efficiencies of at least 6.5 wt% H-2.

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