The Friedel-​Crafts acetylation of naphthalene. Evidence for concurrent second- and third-​order reactions

Fadhil S. Kamounah, Andreas D. Andreou, Roger V. Bulbulian, P.H. Gore, A.Y. Miri, David N. Waters

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

Abstract

The Friedel–Crafts acetylation of naphthalene has been shown to give varying α : β isomer ratios as a function of concentration of the reactants. In consequence the ratio is strongly time- and temperature-dependent. Values of the α : β ratio (determined by an extrapolation procedure, for 1,2-dichloroethane solution) for the limit of zero reaction time, were plotted against reactant concentration, to give a straight line having a near-zero intercept. From this it is inferred that, whereas β-acetylation is essentially first-order with respect to the acylating reagent, α-acetylation is dominantly second-order in acylating reagent.
OriginalsprogEngelsk
Artikelnummer55
TidsskriftJournal of the Chemical Society. Perkin Transactions 2 (2001)
Vol/bind2
Sider (fra-til)376-378
Antal sider3
ISSN1472-779X
DOI
StatusUdgivet - 1981
Udgivet eksterntJa

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