Synthesis and characterisation of nonclassical ruthenium hydride complexes containing chelating bidentate and tridentate phosphine ligands

Martin H. G. Prechtl; Y. Ben-David; D. Giunta; S. Busch; Y. Taniguchi; W. Wisniewski; H. Gorls; R. J. Mynott; N. Theyssen; D. Milstein; W. Leitner

doi:10.1002/chem.200600897

Synthesis and characterisation of nonclassical ruthenium hydride complexes containing chelating bidentate and tridentate phosphine ligands

Martin H. G. Prechtl, Y. Ben-David, D. Giunta, S. Busch, Y. Taniguchi, W. Wisniewski, H. Gorls, R. J. Mynott, N. Theyssen, D. Milstein, W. Leitner

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Abstract

The synthesis and characterisation of nonclassical ruthenium hydride complexes containing bidentate PP and tridentate PCP and PNP pincer-type ligands are described. The mononuclear and dinuclear ruthenium complexes presented have been synthesised in moderate to high yields by the direct hydrogenation route (one-pot synthesis) or in a two-step procedure. In both cases [Ru(cod)(metallyl)(2)] served as a readily available precursor. The influences of the coordination geometry and the ligand framework on the structure, binding, and chemical properties of the M-H, fragments were studied by X-ray crystal structure analysis, spectroscopic methods, and reactivity towards N-2, D-2, and deuterated solvents.

Originalsprog	Engelsk
Tidsskrift	Chemistry: A European Journal
Vol/bind	13
Udgave nummer	5
Sider (fra-til)	1539-1546
Antal sider	8
ISSN	0947-6539
DOI	https://doi.org/10.1002/chem.200600897
Status	Udgivet - 2007
Udgivet eksternt	Ja

Link til dokument

10.1002/chem.200600897

Citer dette

Prechtl, M. H. G., Ben-David, Y., Giunta, D., Busch, S., Taniguchi, Y., Wisniewski, W., Gorls, H., Mynott, R. J., Theyssen, N., Milstein, D., & Leitner, W. (2007). Synthesis and characterisation of nonclassical ruthenium hydride complexes containing chelating bidentate and tridentate phosphine ligands. Chemistry: A European Journal, 13(5), 1539-1546. https://doi.org/10.1002/chem.200600897

@article{02ae40ac51db4d9899e41b11bba4078d,

title = "Synthesis and characterisation of nonclassical ruthenium hydride complexes containing chelating bidentate and tridentate phosphine ligands",

abstract = "The synthesis and characterisation of nonclassical ruthenium hydride complexes containing bidentate PP and tridentate PCP and PNP pincer-type ligands are described. The mononuclear and dinuclear ruthenium complexes presented have been synthesised in moderate to high yields by the direct hydrogenation route (one-pot synthesis) or in a two-step procedure. In both cases [Ru(cod)(metallyl)(2)] served as a readily available precursor. The influences of the coordination geometry and the ligand framework on the structure, binding, and chemical properties of the M-H, fragments were studied by X-ray crystal structure analysis, spectroscopic methods, and reactivity towards N-2, D-2, and deuterated solvents.",

keywords = "chelates dihydrogen complexes hydrides phosphine ligands ruthenium 16-electron dihydrogen complexes zerovalent olefinic derivatives molecular-hydrogen complexes ray crystal-structure sp(3) c-h pincer complexes bond activation polyhydride complexes electronic-structure neutron structure Chemistry",

author = "Prechtl, {Martin H. G.} and Y. Ben-David and D. Giunta and S. Busch and Y. Taniguchi and W. Wisniewski and H. Gorls and Mynott, {R. J.} and N. Theyssen and D. Milstein and W. Leitner",

note = "ISI Document Delivery No.: 136KG Times Cited: 29 Cited Reference Count: 51 Cited References: Abdur-Rashid K, 2000, ORGANOMETALLICS, V19, P1652, DOI 10.1021/om990669i Amoroso D, 2004, ORGANOMETALLICS, V23, P4047, DOI 10.1021/om040025x ARLIGUIE T, 1988, INORG CHEM, V27, P598, DOI 10.1021/ic00277a006 BALDERRAIN TR, 1997, ORGANOMETALLICS, V16, P4001 Borowski AF, 1996, ORGANOMETALLICS, V15, P1427, DOI 10.1021/om950888d Borowski AF, 2000, CHEM COMMUN, P543, DOI 10.1039/a908567j Busch S, 1999, CHEM COMMUN, P2305, DOI 10.1039/a906580f Busch S, 2001, ADV SYNTH CATAL, V343, P192, DOI 10.1002/1615-4169(20010226)343:2<192::AID-ADSC192>3.0.CO;2-S Buskens P, 2004, INORG CHIM ACTA, V357, P1969, DOI 10.1016/j.ica.2004.01.018 CHAUDRET B, 1985, ORGANOMETALLICS, V4, P1722, DOI 10.1021/om00129a005 CHAUDRET B, 1991, J AM CHEM SOC, V113, P2314, DOI 10.1021/ja00006a067 CHAUDRET B, 1985, ORGANOMETALLICS, V4, P1727, DOI 10.1021/om00129a006 CHRIST ML, 1994, ORGANOMETALLICS, V13, P3800, DOI 10.1021/om00022a014 CHUNG G, 1992, NEW J CHEM, V16, P369 CRABTREE RH, 1990, ACCOUNTS CHEM RES, V23, P95, DOI 10.1021/ar00172a001 Darensbourg MY, 2000, COORDIN CHEM REV, V206, P533, DOI 10.1016/S0010-8545(00)00268-X Dedieu A., 1990, TRANSITION METAL HYD Delpech F, 1998, ORGANOMETALLICS, V17, P4926, DOI 10.1021/om9805180 Farrington EJ, 2002, CHEM COMMUN, P308, DOI 10.1039/b108585a Giunta D, 2003, ADV SYNTH CATAL, V345, P1139, DOI 10.1002/adsc.200303091 Grellier M, 2005, J AM CHEM SOC, V127, P17592, DOI 10.1021/ja055126g Guari Y, 1998, J AM CHEM SOC, V120, P4228, DOI 10.1021/ja971603m Guari Y, 2004, J MOL CATAL A-CHEM, V212, P77, DOI 10.1016/j.molcata.2003.10.034 Gusev DG, 2002, ORGANOMETALLICS, V21, P1095, DOI 10.1021/om010771r Gusev DG, 2000, ORGANOMETALLICS, V19, P3429, DOI 10.1021/om0003842 HEINEKEY DM, 1993, CHEM REV, V93, P913, DOI 10.1021/cr00019a004 Hermann D, 2002, ORGANOMETALLICS, V21, P812, DOI 10.1021/om010719v HOFMANN P, 1992, CHEM BER-RECL, V125, P353, DOI 10.1002/cber.19921250212 JESSOP PG, 1992, COORDIN CHEM REV, V121, P155, DOI 10.1016/0010-8545(92)80067-2 Jia GC, 1998, ORGANOMETALLICS, V17, P4538, DOI 10.1021/om9805640 Kawatsura M, 2001, ORGANOMETALLICS, V20, P1960, DOI 10.1021/om0009987 KJOSHI AM, 1995, J ORGANOMET CHEM, V488, P161 KUBAS G, 2001, METAL DIHYDROGEN ALP KUBAS GJ, 1993, J AM CHEM SOC, V115, P569, DOI 10.1021/ja00055a029 KUBAS GJ, 1988, ACCOUNTS CHEM RES, V21, P120, DOI 10.1021/ar00147a005 Kubas GJ, 2001, J ORGANOMET CHEM, V635, P37, DOI 10.1016/S0022-328X(01)01066-X KUBAS GJ, 1984, J AM CHEM SOC, V106, P451, DOI 10.1021/ja00314a049 Leitner W, 1999, ORGANOMETALLICS, V18, P1196, DOI 10.1021/om980980k Lenero KA, 2003, INORG CHEM, V42, P2859, DOI 10.1021/ic020577c Major Q, 2005, ORGANOMETALLICS, V24, P2492, DOI 10.1021/om050053v MOULTON CJ, 1976, J CHEM SOC DALTON, P1020, DOI 10.1039/dt9760001020 PACIELLO RA, 1996, Patent No. 9623802 PERRIN DD, PURIFICATION LAB CHE Six C, 1999, ORGANOMETALLICS, V18, P3316, DOI 10.1021/om990229r van der Boom ME, 2003, CHEM REV, V103, P1759, DOI 10.1021/cr960118r van der Boom ME, 2004, INORG CHIM ACTA, V357, P1854, DOI 10.1016/j.ica.2003.11.014 van der Boom ME, 1999, ORGANOMETALLICS, V18, P3873, DOI 10.1021/om990282f WOODWARD LA, 1972, INTRO THEORY MOL VIB, P207 Zhang J., 2006, ANGEW CHEM, V118, P1131, DOI 10.1002/ange.200503771 Zhang J, 2006, ANGEW CHEM INT EDIT, V45, P1113, DOI 10.1002/anie.200503771 Zhang J, 2005, J AM CHEM SOC, V127, P10840, DOI 10.1021/ja052862b Prechtl, Martin H. G. Ben-David, Yehoshoa Giunta, Daniela Busch, Stefan Taniguchi, Yuki Wisniewski, Wolfgang Goerls, Helmar Mynott, Richard J. Theyssen, Nils Milstein, David Leitner, Walter Prechtl, Martin/A-7416-2008 Prechtl, Martin/0000-0003-2155-8006 29 Wiley-v c h verlag gmbh Weinheim",

year = "2007",

doi = "10.1002/chem.200600897",

language = "English",

volume = "13",

pages = "1539--1546",

journal = "Chemistry: A European Journal",

issn = "0947-6539",

publisher = "Wiley - V C H Verlag GmbH & Co. KGaA",

number = "5",

}

Prechtl, MHG, Ben-David, Y, Giunta, D, Busch, S, Taniguchi, Y, Wisniewski, W, Gorls, H, Mynott, RJ, Theyssen, N, Milstein, D & Leitner, W 2007, 'Synthesis and characterisation of nonclassical ruthenium hydride complexes containing chelating bidentate and tridentate phosphine ligands', Chemistry: A European Journal, bind 13, nr. 5, s. 1539-1546. https://doi.org/10.1002/chem.200600897

TY - JOUR

T1 - Synthesis and characterisation of nonclassical ruthenium hydride complexes containing chelating bidentate and tridentate phosphine ligands

AU - Prechtl, Martin H. G.

AU - Ben-David, Y.

AU - Giunta, D.

AU - Busch, S.

AU - Taniguchi, Y.

AU - Wisniewski, W.

AU - Gorls, H.

AU - Mynott, R. J.

AU - Theyssen, N.

AU - Milstein, D.

AU - Leitner, W.

N1 - ISI Document Delivery No.: 136KG Times Cited: 29 Cited Reference Count: 51 Cited References: Abdur-Rashid K, 2000, ORGANOMETALLICS, V19, P1652, DOI 10.1021/om990669i Amoroso D, 2004, ORGANOMETALLICS, V23, P4047, DOI 10.1021/om040025x ARLIGUIE T, 1988, INORG CHEM, V27, P598, DOI 10.1021/ic00277a006 BALDERRAIN TR, 1997, ORGANOMETALLICS, V16, P4001 Borowski AF, 1996, ORGANOMETALLICS, V15, P1427, DOI 10.1021/om950888d Borowski AF, 2000, CHEM COMMUN, P543, DOI 10.1039/a908567j Busch S, 1999, CHEM COMMUN, P2305, DOI 10.1039/a906580f Busch S, 2001, ADV SYNTH CATAL, V343, P192, DOI 10.1002/1615-4169(20010226)343:2<192::AID-ADSC192>3.0.CO;2-S Buskens P, 2004, INORG CHIM ACTA, V357, P1969, DOI 10.1016/j.ica.2004.01.018 CHAUDRET B, 1985, ORGANOMETALLICS, V4, P1722, DOI 10.1021/om00129a005 CHAUDRET B, 1991, J AM CHEM SOC, V113, P2314, DOI 10.1021/ja00006a067 CHAUDRET B, 1985, ORGANOMETALLICS, V4, P1727, DOI 10.1021/om00129a006 CHRIST ML, 1994, ORGANOMETALLICS, V13, P3800, DOI 10.1021/om00022a014 CHUNG G, 1992, NEW J CHEM, V16, P369 CRABTREE RH, 1990, ACCOUNTS CHEM RES, V23, P95, DOI 10.1021/ar00172a001 Darensbourg MY, 2000, COORDIN CHEM REV, V206, P533, DOI 10.1016/S0010-8545(00)00268-X Dedieu A., 1990, TRANSITION METAL HYD Delpech F, 1998, ORGANOMETALLICS, V17, P4926, DOI 10.1021/om9805180 Farrington EJ, 2002, CHEM COMMUN, P308, DOI 10.1039/b108585a Giunta D, 2003, ADV SYNTH CATAL, V345, P1139, DOI 10.1002/adsc.200303091 Grellier M, 2005, J AM CHEM SOC, V127, P17592, DOI 10.1021/ja055126g Guari Y, 1998, J AM CHEM SOC, V120, P4228, DOI 10.1021/ja971603m Guari Y, 2004, J MOL CATAL A-CHEM, V212, P77, DOI 10.1016/j.molcata.2003.10.034 Gusev DG, 2002, ORGANOMETALLICS, V21, P1095, DOI 10.1021/om010771r Gusev DG, 2000, ORGANOMETALLICS, V19, P3429, DOI 10.1021/om0003842 HEINEKEY DM, 1993, CHEM REV, V93, P913, DOI 10.1021/cr00019a004 Hermann D, 2002, ORGANOMETALLICS, V21, P812, DOI 10.1021/om010719v HOFMANN P, 1992, CHEM BER-RECL, V125, P353, DOI 10.1002/cber.19921250212 JESSOP PG, 1992, COORDIN CHEM REV, V121, P155, DOI 10.1016/0010-8545(92)80067-2 Jia GC, 1998, ORGANOMETALLICS, V17, P4538, DOI 10.1021/om9805640 Kawatsura M, 2001, ORGANOMETALLICS, V20, P1960, DOI 10.1021/om0009987 KJOSHI AM, 1995, J ORGANOMET CHEM, V488, P161 KUBAS G, 2001, METAL DIHYDROGEN ALP KUBAS GJ, 1993, J AM CHEM SOC, V115, P569, DOI 10.1021/ja00055a029 KUBAS GJ, 1988, ACCOUNTS CHEM RES, V21, P120, DOI 10.1021/ar00147a005 Kubas GJ, 2001, J ORGANOMET CHEM, V635, P37, DOI 10.1016/S0022-328X(01)01066-X KUBAS GJ, 1984, J AM CHEM SOC, V106, P451, DOI 10.1021/ja00314a049 Leitner W, 1999, ORGANOMETALLICS, V18, P1196, DOI 10.1021/om980980k Lenero KA, 2003, INORG CHEM, V42, P2859, DOI 10.1021/ic020577c Major Q, 2005, ORGANOMETALLICS, V24, P2492, DOI 10.1021/om050053v MOULTON CJ, 1976, J CHEM SOC DALTON, P1020, DOI 10.1039/dt9760001020 PACIELLO RA, 1996, Patent No. 9623802 PERRIN DD, PURIFICATION LAB CHE Six C, 1999, ORGANOMETALLICS, V18, P3316, DOI 10.1021/om990229r van der Boom ME, 2003, CHEM REV, V103, P1759, DOI 10.1021/cr960118r van der Boom ME, 2004, INORG CHIM ACTA, V357, P1854, DOI 10.1016/j.ica.2003.11.014 van der Boom ME, 1999, ORGANOMETALLICS, V18, P3873, DOI 10.1021/om990282f WOODWARD LA, 1972, INTRO THEORY MOL VIB, P207 Zhang J., 2006, ANGEW CHEM, V118, P1131, DOI 10.1002/ange.200503771 Zhang J, 2006, ANGEW CHEM INT EDIT, V45, P1113, DOI 10.1002/anie.200503771 Zhang J, 2005, J AM CHEM SOC, V127, P10840, DOI 10.1021/ja052862b Prechtl, Martin H. G. Ben-David, Yehoshoa Giunta, Daniela Busch, Stefan Taniguchi, Yuki Wisniewski, Wolfgang Goerls, Helmar Mynott, Richard J. Theyssen, Nils Milstein, David Leitner, Walter Prechtl, Martin/A-7416-2008 Prechtl, Martin/0000-0003-2155-8006 29 Wiley-v c h verlag gmbh Weinheim

PY - 2007

Y1 - 2007

N2 - The synthesis and characterisation of nonclassical ruthenium hydride complexes containing bidentate PP and tridentate PCP and PNP pincer-type ligands are described. The mononuclear and dinuclear ruthenium complexes presented have been synthesised in moderate to high yields by the direct hydrogenation route (one-pot synthesis) or in a two-step procedure. In both cases [Ru(cod)(metallyl)(2)] served as a readily available precursor. The influences of the coordination geometry and the ligand framework on the structure, binding, and chemical properties of the M-H, fragments were studied by X-ray crystal structure analysis, spectroscopic methods, and reactivity towards N-2, D-2, and deuterated solvents.

AB - The synthesis and characterisation of nonclassical ruthenium hydride complexes containing bidentate PP and tridentate PCP and PNP pincer-type ligands are described. The mononuclear and dinuclear ruthenium complexes presented have been synthesised in moderate to high yields by the direct hydrogenation route (one-pot synthesis) or in a two-step procedure. In both cases [Ru(cod)(metallyl)(2)] served as a readily available precursor. The influences of the coordination geometry and the ligand framework on the structure, binding, and chemical properties of the M-H, fragments were studied by X-ray crystal structure analysis, spectroscopic methods, and reactivity towards N-2, D-2, and deuterated solvents.

KW - chelates dihydrogen complexes hydrides phosphine ligands ruthenium 16-electron dihydrogen complexes zerovalent olefinic derivatives molecular-hydrogen complexes ray crystal-structure sp(3) c-h pincer complexes bond activation polyhydride complexes electro

U2 - 10.1002/chem.200600897

DO - 10.1002/chem.200600897

M3 - Journal article

SN - 0947-6539

VL - 13

SP - 1539

EP - 1546

JO - Chemistry: A European Journal

JF - Chemistry: A European Journal

IS - 5

ER -