Stereoselective iron-catalyzed alkyne hydrogenation in ionic liquids

Tim N. Gieshoff; Alice Welther; Michael T. Kessler; Martin H. G. Prechtl; Axel Jacobi von Wangelin

doi:10.1039/c3cc49679a

Stereoselective iron-catalyzed alkyne hydrogenation in ionic liquids

Tim N. Gieshoff, Alice Welther, Michael T. Kessler, Martin H. G. Prechtl, Axel Jacobi von Wangelin

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Abstract

Iron(0) nanoparticles in ionic liquids (ILs) have been shown to catalyse the semi-hydrogenation of alkynes. In the presence of a nitrile-functionalised IL or acetonitrile, stereoselective formation of (Z)-alkenes was observed. The biphasic solvent system allowed facile separation and re-use of the catalyst.

Originalsprog	Engelsk
Tidsskrift	Chemical Communications
Vol/bind	50
Udgave nummer	18
Sider (fra-til)	2261-2264
Antal sider	4
ISSN	1359-7345
DOI	https://doi.org/10.1039/c3cc49679a
Status	Udgivet - 2014
Udgivet eksternt	Ja

Link til dokument

10.1039/c3cc49679aLicens: CC BY

c3cc49679aForlagets udgivne version, 1,28 MBLicens: CC BY

Citer dette

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abstract = "Iron(0) nanoparticles in ionic liquids (ILs) have been shown to catalyse the semi-hydrogenation of alkynes. In the presence of a nitrile-functionalised IL or acetonitrile, stereoselective formation of (Z)-alkenes was observed. The biphasic solvent system allowed facile separation and re-use of the catalyst.",

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AB - Iron(0) nanoparticles in ionic liquids (ILs) have been shown to catalyse the semi-hydrogenation of alkynes. In the presence of a nitrile-functionalised IL or acetonitrile, stereoselective formation of (Z)-alkenes was observed. The biphasic solvent system allowed facile separation and re-use of the catalyst.

U2 - 10.1039/c3cc49679a

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