Stereoselective iron-catalyzed alkyne hydrogenation in ionic liquids

Tim N. Gieshoff, Alice Welther, Michael T. Kessler, Martin H. G. Prechtl, Axel Jacobi von Wangelin

Publikation: Bidrag til tidsskriftTidsskriftartikelpeer review

Abstract

Iron(0) nanoparticles in ionic liquids (ILs) have been shown to catalyse the semi-hydrogenation of alkynes. In the presence of a nitrile-functionalised IL or acetonitrile, stereoselective formation of (Z)-alkenes was observed. The biphasic solvent system allowed facile separation and re-use of the catalyst.
OriginalsprogEngelsk
TidsskriftChemical Communications
Vol/bind50
Udgave nummer18
Sider (fra-til)2261-2264
Antal sider4
ISSN1359-7345
DOI
StatusUdgivet - 2014
Udgivet eksterntJa

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