Solid state tautomerism in 2-((phenylimino)methyl)naphthalene-1-ol

Daniela Nedeltcheva; Fadhil S. Kamounah; Laurent Mirolo; Katharina M. Fromm; Liudmil Antonov

Solid state tautomerism in 2-((phenylimino)methyl)naphthalene-1-ol

Daniela Nedeltcheva, Fadhil S. Kamounah, Laurent Mirolo, Katharina M. Fromm, Liudmil Antonov

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Abstract

The solid state tautomerism of 2-((phenylimino)methyl)naphthalene-1-ol was studied using X-ray measurements and absorption spectroscopy. In the solid state, the keto tautomer predominates. The observed shift in the equilibrium from the enol (dilute solution) to the keto (solid state) forms is explained by the formation of dye aggregates using ab initio quantum chemical calculations

Originalsprog	Engelsk
Tidsskrift	Dyes and Pigments
Vol/bind	83
Udgave nummer	1
Sider (fra-til)	121-126
ISSN	0143-7208
Status	Udgivet - 2009

Citer dette

@article{f1ab9e30f9fa11de89af000ea68e967b,

title = "Solid state tautomerism in 2-((phenylimino)methyl)naphthalene-1-ol",

abstract = "The solid state tautomerism of 2-((phenylimino)methyl)naphthalene-1-ol was studied using X-ray measurements and absorption spectroscopy. In the solid state, the keto tautomer predominates. The observed shift in the equilibrium from the enol (dilute solution) to the keto (solid state) forms is explained by the formation of dye aggregates using ab initio quantum chemical calculations",

keywords = "Tautomerism, Schiff bases, Intramolecular proton transfer, Crystallography, Spectroscopy, Photochromic dyes",

author = "Daniela Nedeltcheva and Kamounah, {Fadhil S.} and Laurent Mirolo and Fromm, {Katharina M.} and Liudmil Antonov",

year = "2009",

language = "English",

volume = "83",

pages = "121--126",

journal = "Dyes and Pigments",

issn = "0143-7208",

publisher = "Pergamon Press",

number = "1",

}

TY - JOUR

T1 - Solid state tautomerism in 2-((phenylimino)methyl)naphthalene-1-ol

AU - Nedeltcheva, Daniela

AU - Kamounah, Fadhil S.

AU - Mirolo, Laurent

AU - Fromm, Katharina M.

AU - Antonov, Liudmil

PY - 2009

Y1 - 2009

N2 - The solid state tautomerism of 2-((phenylimino)methyl)naphthalene-1-ol was studied using X-ray measurements and absorption spectroscopy. In the solid state, the keto tautomer predominates. The observed shift in the equilibrium from the enol (dilute solution) to the keto (solid state) forms is explained by the formation of dye aggregates using ab initio quantum chemical calculations

AB - The solid state tautomerism of 2-((phenylimino)methyl)naphthalene-1-ol was studied using X-ray measurements and absorption spectroscopy. In the solid state, the keto tautomer predominates. The observed shift in the equilibrium from the enol (dilute solution) to the keto (solid state) forms is explained by the formation of dye aggregates using ab initio quantum chemical calculations

KW - Tautomerism

KW - Schiff bases

KW - Intramolecular proton transfer

KW - Crystallography

KW - Spectroscopy

KW - Photochromic dyes

M3 - Journal article

SN - 0143-7208

VL - 83

SP - 121

EP - 126

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 1

ER -