Rate of homogeneous electron-transfer in self-exchange reactions of methylviologen

René Fuhlendorff; Torben Lund; Henning Lund; Jens Arne Pedersen

doi:10.1016/S0040-4039(00)96723-6

Rate of homogeneous electron-transfer in self-exchange reactions of methylviologen

René Fuhlendorff, Torben Lund, Henning Lund^*, Jens Arne Pedersen^*

^*Corresponding author

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Abstract

The rate of the self-exchange reactions between 1,1′-dimethyl-4,4′-bipyridinium diperchlorate (methylviologen, MV²⁺) and its one-electron reduction product (MV⁺•) and between MV⁺• and the two-electron reduction product (MV) is measured from the broadening of the lines in the ESR-spectrum of MV⁺• in DMF. The bond and solvent reorganization energies λ(O) of these reactions are calculated.

Originalsprog	Engelsk
Tidsskrift	Tetrahedron Letters
Vol/bind	28
Udgave nummer	44
Sider (fra-til)	5335-5338
Antal sider	4
ISSN	0040-4039
DOI	https://doi.org/10.1016/S0040-4039(00)96723-6
Status	Udgivet - 1987
Udgivet eksternt	Ja

Link til dokument

10.1016/S0040-4039(00)96723-6

Citer dette

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title = "Rate of homogeneous electron-transfer in self-exchange reactions of methylviologen",

abstract = "The rate of the self-exchange reactions between 1,1′-dimethyl-4,4′-bipyridinium diperchlorate (methylviologen, MV2+) and its one-electron reduction product (MV+•) and between MV+• and the two-electron reduction product (MV) is measured from the broadening of the lines in the ESR-spectrum of MV+• in DMF. The bond and solvent reorganization energies λ(O) of these reactions are calculated.",

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AU - Fuhlendorff, René

AU - Lund, Torben

AU - Lund, Henning

AU - Pedersen, Jens Arne

PY - 1987

Y1 - 1987

N2 - The rate of the self-exchange reactions between 1,1′-dimethyl-4,4′-bipyridinium diperchlorate (methylviologen, MV2+) and its one-electron reduction product (MV+•) and between MV+• and the two-electron reduction product (MV) is measured from the broadening of the lines in the ESR-spectrum of MV+• in DMF. The bond and solvent reorganization energies λ(O) of these reactions are calculated.

AB - The rate of the self-exchange reactions between 1,1′-dimethyl-4,4′-bipyridinium diperchlorate (methylviologen, MV2+) and its one-electron reduction product (MV+•) and between MV+• and the two-electron reduction product (MV) is measured from the broadening of the lines in the ESR-spectrum of MV+• in DMF. The bond and solvent reorganization energies λ(O) of these reactions are calculated.

U2 - 10.1016/S0040-4039(00)96723-6

DO - 10.1016/S0040-4039(00)96723-6

M3 - Journal article

AN - SCOPUS:0011332973

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VL - 28

SP - 5335

EP - 5338

JO - Tetrahedron Letters

JF - Tetrahedron Letters

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