Abstract
Conversion of acetyl cedrene (2) to its follower (3) using acetic anhydride and polyphosphoric acid involves a multi-step cationic molecular rearrangement, which is consistent with deuteriation and 1-13C labeling studies of acetyl cedrene. The key step involves cyclopropylcarbinyl cation-cyclopropylcarbinyl cation rearrangement.
Originalsprog | Engelsk |
---|---|
Tidsskrift | Chemistry of Natural Compounds |
Vol/bind | 53 |
Udgave nummer | 4 |
Sider (fra-til) | 661-664 |
Antal sider | 4 |
ISSN | 0009-3130 |
DOI | |
Status | Udgivet - 2017 |
Emneord
- 13C labelling
- acetyl cedrene
- deuterium exchange
- follower
- reaction mechanism