### Abstract

This paper derives and discusses the configuration-space Langevin equation describing a physically aging R-simple system and the corresponding Smoluchowski equation. Externally controlled thermodynamic variables like temperature, density, and pressure enter the description via the single parameter Ts/T, in which T is the bath temperature and Ts is the “systemic” temperature defined at any time t as the thermodynamic equilibrium temperature of the state point with density ρ(t) and potential energy U(t). In equilibrium, Ts ≅ T with fluctuations that vanish in the thermodynamic limit. In contrast to Tool’s fictive temperature and other effective temperatures in glass science, the systemic temperature is defined for any configuration with a well-defined density, even if it is not close to equilibrium. Density and systemic temperature define an aging phase diagram, in which the aging system traces out a curve. Predictions are discussed for aging following various density-temperature and pressure-temperature jumps from one equilibrium state to another, as well as for a few other scenarios. The proposed theory implies that R-simple glass-forming liquids are characterized by the dynamic Prigogine-Defay ratio being equal to unity

Originalsprog | Engelsk |
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Artikelnummer | 154502 |

Tidsskrift | Journal of Chemical Physics |

Vol/bind | 148 |

ISSN | 0021-9606 |

DOI | |

Status | Udgivet - 2018 |

## Citer dette

Dyre, J. (2018). Isomorph theory of physical aging.

*Journal of Chemical Physics*,*148*, [154502]. https://doi.org/10.1063/1.5022999