Solid-that-Flows Picture of Glass-Forming Liquids

This perspective article reviews arguments that glass-forming liquids are different from those of standard liquid-state theory, which typically have a viscosity in the mPa·s range and relaxation times on the order of picoseconds. These numbers grow dramatically and become 10¹² - 10¹⁵ times larger for liquids cooled toward the glass transition. This translates into a qualitative difference, and below the “solidity length” which is roughly one micron at the glass transition, a glass-forming liquid behaves much like a solid. Recent numerical evidence for the solidity of ultraviscous liquids is reviewed, and experimental consequences are discussed in relation to dynamic heterogeneity, frequency-dependent linear-response functions, and the temperature dependence of the average relaxation time.