Isochronal superposition and density scaling of the α-relaxation from pico- to millisecond

Henriette Wase Hansen, Bernhard Frick, Simone Capaccioli, Alejandro Sanz, Kristine Niss

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

Resumé

The relaxation dynamics in two van der Waals bonded liquids and one hydrogen-bonding molecular
liquid are studied as a function of pressure and temperature by incoherent neutron scattering
using simultaneous dielectric spectroscopy. The dynamics are studied in a range of alpha relaxation
times from pico- to milliseconds, primarily in the equilibrium liquid state. In this range, we find that
isochronal superposition and density scaling work not only for the two van derWaals liquids but also for
the hydrogen-bonding liquid, though the density scaling exponent is much smaller for the latter. Density
scaling and isochronal superposition are seen to break down for intra-molecular dynamics when
it is separated in time from the alpha relaxation, in close agreement with previous observations from
molecular dynamics simulations.
OriginalsprogEngelsk
Artikelnummer214503
TidsskriftJournal of Chemical Physics
Vol/bind149
Udgave nummer21
ISSN0021-9606
DOI
StatusUdgivet - 2018

Bibliografisk note

This article has been found as a ’Free Version’ from the Publisher on December 20 2019. When access to the article closes, please notify rucforsk@ruc.dk

Citer dette

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abstract = "The relaxation dynamics in two van der Waals bonded liquids and one hydrogen-bonding molecular liquid are studied as a function of pressure and temperature by incoherent neutron scattering using simultaneous dielectric spectroscopy. The dynamics are studied in a range of alpha relaxation times from pico- to milliseconds, primarily in the equilibrium liquid state. In this range, we find that isochronal superposition and density scaling work not only for the two van der Waals liquids but also for the hydrogen-bonding liquid, though the density scaling exponent is much smaller for the latter. Density scaling and isochronal superposition are seen to break down for intra-molecular dynamics when it is separated in time from the alpha relaxation, in close agreement with previous observations from molecular dynamics simulations.I. INTRODUCTION",
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Isochronal superposition and density scaling of the α-relaxation from pico- to millisecond. / Hansen, Henriette Wase; Frick, Bernhard; Capaccioli, Simone; Sanz, Alejandro; Niss, Kristine.

I: Journal of Chemical Physics, Bind 149, Nr. 21, 214503, 2018.

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

TY - JOUR

T1 - Isochronal superposition and density scaling of the α-relaxation from pico- to millisecond

AU - Hansen, Henriette Wase

AU - Frick, Bernhard

AU - Capaccioli, Simone

AU - Sanz, Alejandro

AU - Niss, Kristine

N1 - This article has been found as a ’Free Version’ from the Publisher on December 20 2019. When access to the article closes, please notify rucforsk@ruc.dk

PY - 2018

Y1 - 2018

N2 - The relaxation dynamics in two van der Waals bonded liquids and one hydrogen-bonding molecular liquid are studied as a function of pressure and temperature by incoherent neutron scattering using simultaneous dielectric spectroscopy. The dynamics are studied in a range of alpha relaxation times from pico- to milliseconds, primarily in the equilibrium liquid state. In this range, we find that isochronal superposition and density scaling work not only for the two van der Waals liquids but also for the hydrogen-bonding liquid, though the density scaling exponent is much smaller for the latter. Density scaling and isochronal superposition are seen to break down for intra-molecular dynamics when it is separated in time from the alpha relaxation, in close agreement with previous observations from molecular dynamics simulations.I. INTRODUCTION

AB - The relaxation dynamics in two van der Waals bonded liquids and one hydrogen-bonding molecular liquid are studied as a function of pressure and temperature by incoherent neutron scattering using simultaneous dielectric spectroscopy. The dynamics are studied in a range of alpha relaxation times from pico- to milliseconds, primarily in the equilibrium liquid state. In this range, we find that isochronal superposition and density scaling work not only for the two van der Waals liquids but also for the hydrogen-bonding liquid, though the density scaling exponent is much smaller for the latter. Density scaling and isochronal superposition are seen to break down for intra-molecular dynamics when it is separated in time from the alpha relaxation, in close agreement with previous observations from molecular dynamics simulations.I. INTRODUCTION

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