Imidazolium ionic liquids as promoters and stabilising agents for the preparation of metal(0) nanoparticles by reduction and decomposition of organometallic complexes

Martin H. G. Prechtl; P. S. Campbell; J. D. Scholten; G. B. Fraser; G. Machado; C. C. Santini; J. Dupont; Y. Chauvin

doi:10.1039/c0nr00574f

Imidazolium ionic liquids as promoters and stabilising agents for the preparation of metal(0) nanoparticles by reduction and decomposition of organometallic complexes

Martin H. G. Prechtl, P. S. Campbell, J. D. Scholten, G. B. Fraser, G. Machado, C. C. Santini, J. Dupont, Y. Chauvin

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Abstract

The organometallic complexes ([Ru(COD)(2-methylallyl)(2)] and [Ni(COD)(2)] (COD = 1,5-cyclooctadiene) dissolved in imidazolium ionic liquids (ILs) undergo reduction and decomposition, respectively, to afford stable ruthenium and nickel metal(0) nanoparticles (Ru(0)-NPs and Ni(0)-NPs) in the absence of classical reducing agents. Depending on the case, the reduction/auto-decomposition is promoted by either the cation and/or anion of the neat imidazolium ILs.

Originalsprog	Engelsk
Tidsskrift	Nanoscale
Vol/bind	2
Udgave nummer	12
Sider (fra-til)	2601-2606
Antal sider	6
ISSN	2040-3364
DOI	https://doi.org/10.1039/c0nr00574f
Status	Udgivet - 2010
Udgivet eksternt	Ja

Link til dokument

10.1039/c0nr00574f

Citer dette

@article{745e66b8d6cf41cbabd76d8bfb1e80e6,

title = "Imidazolium ionic liquids as promoters and stabilising agents for the preparation of metal(0) nanoparticles by reduction and decomposition of organometallic complexes",

abstract = "The organometallic complexes ([Ru(COD)(2-methylallyl)(2)] and [Ni(COD)(2)] (COD = 1,5-cyclooctadiene) dissolved in imidazolium ionic liquids (ILs) undergo reduction and decomposition, respectively, to afford stable ruthenium and nickel metal(0) nanoparticles (Ru(0)-NPs and Ni(0)-NPs) in the absence of classical reducing agents. Depending on the case, the reduction/auto-decomposition is promoted by either the cation and/or anion of the neat imidazolium ILs.",

keywords = "heterocyclic carbene complexes size-dependent formation nickel nanoparticles ruthenium catalysts oxidative addition coupling reactions rhodium complexes hydrogenation salts anion Chemistry Science & Technology - Other Topics Materials Science Physics",

author = "Prechtl, {Martin H. G.} and Campbell, {P. S.} and Scholten, {J. D.} and Fraser, {G. B.} and G. Machado and Santini, {C. C.} and J. Dupont and Y. Chauvin",

note = "ISI Document Delivery No.: 705UY Times Cited: 19 Cited Reference Count: 49 Cited References: Bini R, 2006, CHEM COMMUN, P897, DOI 10.1039/b514988f BOENNEMANN H, 2008, NANOPARTICLES CATALY BOENNEMANN H, 2008, NANOCLUSTERS CATALYS, P21 CAMPBELL PS, 2010, J CATAL, V257, P99 Campbell PS, 2010, PHYS CHEM CHEM PHYS, V12, P4217, DOI 10.1039/b925329g Cassol CC, 2006, ADV SYNTH CATAL, V348, P243, DOI 10.1002/adsc.200505295 Choi S, 2007, KOREAN J CHEM ENG, V24, P856, DOI 10.1007/s11814-007-0054-2 Chowdhury S, 2007, TETRAHEDRON, V63, P2363, DOI 10.1016/j.tet.2006.11.001 Clement ND, 2004, ANGEW CHEM INT EDIT, V43, P1277, DOI 10.1002/anie.200353409 Cordente N, 2003, J APPL PHYS, V94, P6358, DOI 10.1063/1.1621081 Cordente N, 2001, NANO LETT, V1, P565, DOI 10.1021/nl0100522 Crudden CM, 2004, COORDIN CHEM REV, V248, P2247, DOI 10.1016/j.ccr.2004.05.013 Cui YG, 2010, PHYS CHEM CHEM PHYS, V12, P1834, DOI 10.1039/b920025h Dupont J, 2010, CHEM SOC REV, V39, P1780, DOI 10.1039/b822551f Fei ZF, 2007, ORGANOMETALLICS, V26, P1588, DOI 10.1021/om060950e Flannigan DJ, 2005, J ORGANOMET CHEM, V690, P3513, DOI 10.1016/j.jorganchem.2005.04.024 Gao Y, 2008, EUR J INORG CHEM, P3769, DOI 10.1002/ejic.200800467 GENET JP, 1991, TETRAHEDRON-ASYMMETR, V2, P43, DOI 10.1016/S0957-4166(00)82155-2 Graham DC, 2007, DALTON T, P4650, DOI 10.1039/b709914b Grundemann S, 2001, CHEM COMMUN, P2274, DOI 10.1039/b107881j Gutel T, 2007, J MATER CHEM, V17, P3290, DOI 10.1039/b706139k Gutel T, 2009, J MATER CHEM, V19, P3624, DOI 10.1039/b821659b Hintermair U, 2008, J ORGANOMET CHEM, V693, P2407, DOI 10.1016/j.jorganchem.2008.04.017 Kim KS, 2006, J MATER CHEM, V16, P1315, DOI 10.1039/b601478j Lecocq V, 2007, OIL GAS SCI TECHNOL, V62, P761, DOI 10.2516/ogst:2007070 Magna L, 2003, ORGANOMETALLICS, V22, P4418, DOI 10.1021/om021057s McGuinness DS, 2002, ORGANOMETALLICS, V21, P175, DOI 10.1021/om010717a Migowski P, 2007, PHYS CHEM CHEM PHYS, V9, P4814, DOI 10.1039/b703979d Migowski P, 2007, CHEM-EUR J, V13, P32, DOI 10.1002/chem.200601438 Migowski P, 2007, J ELECTRON SPECTROSC, V156, P195, DOI 10.1016/j.elspec.2006.11.027 Migowski P, 2010, PHYS CHEM CHEM PHYS, V12, P6826, DOI 10.1039/b925834e Ott LS, 2006, INORG CHEM, V45, P8382, DOI 10.1021/ic060876s Ott LS, 2007, INORG CHEM, V46, P10335, DOI 10.1021/ic700976z Ott LS, 2005, J AM CHEM SOC, V127, P5758, DOI 10.1021/ja0423320 Oxley JD, 2003, J AM CHEM SOC, V125, P11138, DOI 10.1021/ja029830y Prechtl MHG, 2008, INORG CHEM, V47, P8995, DOI 10.1021/ic801014f Prechtl MHG, 2009, J MOL CATAL A-CHEM, V313, P74, DOI 10.1016/j.molcata.2009.08.004 Prechtl MHG, 2010, MOLECULES, V15, P3441, DOI 10.3390/molecules15053441 Redel E, 2008, INORG CHEM, V47, P14, DOI 10.1021/ic702071w Redel E, 2008, CHEM COMMUN, P1789, DOI 10.1039/b718055a Ryu HJ, 2008, ANGEW CHEM INT EDIT, V47, P7639, DOI 10.1002/anie.200802185 Scariot M, 2008, ANGEW CHEM INT EDIT, V47, P9075, DOI 10.1002/anie.200804200 Scholten J. D., 2009, IRIDIUM COMPLEXES OR, P369 Scholten JD, 2007, DALTON T, P5554, DOI 10.1039/b707888a Scholten JD, 2008, ORGANOMETALLICS, V27, P4439, DOI 10.1021/om8003948 Silva DO, 2008, CHEMSUSCHEM, V1, P291, DOI 10.1002/cssc.200800022 Silveira ET, 2004, CHEM-EUR J, V10, P3734, DOI 10.1002/chem.200305765 Sowmiah S, 2009, MOLECULES, V14, P3780, DOI 10.3390/molecules14093780 Zhao L, 2008, J AM CHEM SOC, V130, P12586, DOI 10.1021/ja8037883 Prechtl, Martin H. G. Campbell, Paul S. Scholten, Jackson D. Fraser, Georgina B. Machado, Giovanna Santini, Catherine C. Dupont, Jairton Chauvin, Yves Dupont, Jairton/F-7161-2010; Prechtl, Martin/A-7416-2008 Prechtl, Martin/0000-0003-2155-8006 ANR [ANR-07-CP2D-02-03]; Ministere de l'enseignement superieur et de la recherche; CNPq; CAPES; INCT-Catal; Alexander-von-Humboldt Foundation; Erasmus programme This work was funded by ANR project CALIST (ANR-07-CP2D-02-03), the {"}Ministere de l'enseignement superieur et de la recherche{"} (P.S.C.), CNPq, CAPES, INCT-Catal. and the Alexander-von-Humboldt Foundation (M. H. G. Prechtl). G.B.F. acknowledges the grant attributed by the Erasmus programme. 19 Royal soc chemistry Cambridge",

year = "2010",

doi = "10.1039/c0nr00574f",

language = "English",

volume = "2",

pages = "2601--2606",

journal = "Nanoscale",

issn = "2040-3364",

number = "12",

}

Imidazolium ionic liquids as promoters and stabilising agents for the preparation of metal(0) nanoparticles by reduction and decomposition of organometallic complexes. / Prechtl, Martin H. G.; Campbell, P. S.; Scholten, J. D.; Fraser, G. B.; Machado, G.; Santini, C. C.; Dupont, J.; Chauvin, Y.

I: Nanoscale, Bind 2, Nr. 12, 2010, s. 2601-2606.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

TY - JOUR

T1 - Imidazolium ionic liquids as promoters and stabilising agents for the preparation of metal(0) nanoparticles by reduction and decomposition of organometallic complexes

AU - Prechtl, Martin H. G.

AU - Campbell, P. S.

AU - Scholten, J. D.

AU - Fraser, G. B.

AU - Machado, G.

AU - Santini, C. C.

AU - Dupont, J.

AU - Chauvin, Y.

N1 - ISI Document Delivery No.: 705UY Times Cited: 19 Cited Reference Count: 49 Cited References: Bini R, 2006, CHEM COMMUN, P897, DOI 10.1039/b514988f BOENNEMANN H, 2008, NANOPARTICLES CATALY BOENNEMANN H, 2008, NANOCLUSTERS CATALYS, P21 CAMPBELL PS, 2010, J CATAL, V257, P99 Campbell PS, 2010, PHYS CHEM CHEM PHYS, V12, P4217, DOI 10.1039/b925329g Cassol CC, 2006, ADV SYNTH CATAL, V348, P243, DOI 10.1002/adsc.200505295 Choi S, 2007, KOREAN J CHEM ENG, V24, P856, DOI 10.1007/s11814-007-0054-2 Chowdhury S, 2007, TETRAHEDRON, V63, P2363, DOI 10.1016/j.tet.2006.11.001 Clement ND, 2004, ANGEW CHEM INT EDIT, V43, P1277, DOI 10.1002/anie.200353409 Cordente N, 2003, J APPL PHYS, V94, P6358, DOI 10.1063/1.1621081 Cordente N, 2001, NANO LETT, V1, P565, DOI 10.1021/nl0100522 Crudden CM, 2004, COORDIN CHEM REV, V248, P2247, DOI 10.1016/j.ccr.2004.05.013 Cui YG, 2010, PHYS CHEM CHEM PHYS, V12, P1834, DOI 10.1039/b920025h Dupont J, 2010, CHEM SOC REV, V39, P1780, DOI 10.1039/b822551f Fei ZF, 2007, ORGANOMETALLICS, V26, P1588, DOI 10.1021/om060950e Flannigan DJ, 2005, J ORGANOMET CHEM, V690, P3513, DOI 10.1016/j.jorganchem.2005.04.024 Gao Y, 2008, EUR J INORG CHEM, P3769, DOI 10.1002/ejic.200800467 GENET JP, 1991, TETRAHEDRON-ASYMMETR, V2, P43, DOI 10.1016/S0957-4166(00)82155-2 Graham DC, 2007, DALTON T, P4650, DOI 10.1039/b709914b Grundemann S, 2001, CHEM COMMUN, P2274, DOI 10.1039/b107881j Gutel T, 2007, J MATER CHEM, V17, P3290, DOI 10.1039/b706139k Gutel T, 2009, J MATER CHEM, V19, P3624, DOI 10.1039/b821659b Hintermair U, 2008, J ORGANOMET CHEM, V693, P2407, DOI 10.1016/j.jorganchem.2008.04.017 Kim KS, 2006, J MATER CHEM, V16, P1315, DOI 10.1039/b601478j Lecocq V, 2007, OIL GAS SCI TECHNOL, V62, P761, DOI 10.2516/ogst:2007070 Magna L, 2003, ORGANOMETALLICS, V22, P4418, DOI 10.1021/om021057s McGuinness DS, 2002, ORGANOMETALLICS, V21, P175, DOI 10.1021/om010717a Migowski P, 2007, PHYS CHEM CHEM PHYS, V9, P4814, DOI 10.1039/b703979d Migowski P, 2007, CHEM-EUR J, V13, P32, DOI 10.1002/chem.200601438 Migowski P, 2007, J ELECTRON SPECTROSC, V156, P195, DOI 10.1016/j.elspec.2006.11.027 Migowski P, 2010, PHYS CHEM CHEM PHYS, V12, P6826, DOI 10.1039/b925834e Ott LS, 2006, INORG CHEM, V45, P8382, DOI 10.1021/ic060876s Ott LS, 2007, INORG CHEM, V46, P10335, DOI 10.1021/ic700976z Ott LS, 2005, J AM CHEM SOC, V127, P5758, DOI 10.1021/ja0423320 Oxley JD, 2003, J AM CHEM SOC, V125, P11138, DOI 10.1021/ja029830y Prechtl MHG, 2008, INORG CHEM, V47, P8995, DOI 10.1021/ic801014f Prechtl MHG, 2009, J MOL CATAL A-CHEM, V313, P74, DOI 10.1016/j.molcata.2009.08.004 Prechtl MHG, 2010, MOLECULES, V15, P3441, DOI 10.3390/molecules15053441 Redel E, 2008, INORG CHEM, V47, P14, DOI 10.1021/ic702071w Redel E, 2008, CHEM COMMUN, P1789, DOI 10.1039/b718055a Ryu HJ, 2008, ANGEW CHEM INT EDIT, V47, P7639, DOI 10.1002/anie.200802185 Scariot M, 2008, ANGEW CHEM INT EDIT, V47, P9075, DOI 10.1002/anie.200804200 Scholten J. D., 2009, IRIDIUM COMPLEXES OR, P369 Scholten JD, 2007, DALTON T, P5554, DOI 10.1039/b707888a Scholten JD, 2008, ORGANOMETALLICS, V27, P4439, DOI 10.1021/om8003948 Silva DO, 2008, CHEMSUSCHEM, V1, P291, DOI 10.1002/cssc.200800022 Silveira ET, 2004, CHEM-EUR J, V10, P3734, DOI 10.1002/chem.200305765 Sowmiah S, 2009, MOLECULES, V14, P3780, DOI 10.3390/molecules14093780 Zhao L, 2008, J AM CHEM SOC, V130, P12586, DOI 10.1021/ja8037883 Prechtl, Martin H. G. Campbell, Paul S. Scholten, Jackson D. Fraser, Georgina B. Machado, Giovanna Santini, Catherine C. Dupont, Jairton Chauvin, Yves Dupont, Jairton/F-7161-2010; Prechtl, Martin/A-7416-2008 Prechtl, Martin/0000-0003-2155-8006 ANR [ANR-07-CP2D-02-03]; Ministere de l'enseignement superieur et de la recherche; CNPq; CAPES; INCT-Catal; Alexander-von-Humboldt Foundation; Erasmus programme This work was funded by ANR project CALIST (ANR-07-CP2D-02-03), the "Ministere de l'enseignement superieur et de la recherche" (P.S.C.), CNPq, CAPES, INCT-Catal. and the Alexander-von-Humboldt Foundation (M. H. G. Prechtl). G.B.F. acknowledges the grant attributed by the Erasmus programme. 19 Royal soc chemistry Cambridge

PY - 2010

Y1 - 2010

N2 - The organometallic complexes ([Ru(COD)(2-methylallyl)(2)] and [Ni(COD)(2)] (COD = 1,5-cyclooctadiene) dissolved in imidazolium ionic liquids (ILs) undergo reduction and decomposition, respectively, to afford stable ruthenium and nickel metal(0) nanoparticles (Ru(0)-NPs and Ni(0)-NPs) in the absence of classical reducing agents. Depending on the case, the reduction/auto-decomposition is promoted by either the cation and/or anion of the neat imidazolium ILs.

AB - The organometallic complexes ([Ru(COD)(2-methylallyl)(2)] and [Ni(COD)(2)] (COD = 1,5-cyclooctadiene) dissolved in imidazolium ionic liquids (ILs) undergo reduction and decomposition, respectively, to afford stable ruthenium and nickel metal(0) nanoparticles (Ru(0)-NPs and Ni(0)-NPs) in the absence of classical reducing agents. Depending on the case, the reduction/auto-decomposition is promoted by either the cation and/or anion of the neat imidazolium ILs.

KW - heterocyclic carbene complexes size-dependent formation nickel nanoparticles ruthenium catalysts oxidative addition coupling reactions rhodium complexes hydrogenation salts anion Chemistry Science & Technology - Other Topics Materials Science Physics

U2 - 10.1039/c0nr00574f

DO - 10.1039/c0nr00574f

M3 - Journal article

VL - 2

SP - 2601

EP - 2606

JO - Nanoscale

JF - Nanoscale

SN - 2040-3364

IS - 12

ER -