Abstract
Originalsprog | Engelsk |
---|---|
Tidsskrift | Nanoscale |
Vol/bind | 2 |
Udgave nummer | 12 |
Sider (fra-til) | 2601-2606 |
Antal sider | 6 |
ISSN | 2040-3364 |
DOI | |
Status | Udgivet - 2010 |
Udgivet eksternt | Ja |
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Imidazolium ionic liquids as promoters and stabilising agents for the preparation of metal(0) nanoparticles by reduction and decomposition of organometallic complexes. / Prechtl, Martin H. G.; Campbell, P. S.; Scholten, J. D.; Fraser, G. B.; Machado, G.; Santini, C. C.; Dupont, J.; Chauvin, Y.
I: Nanoscale, Bind 2, Nr. 12, 2010, s. 2601-2606.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review
TY - JOUR
T1 - Imidazolium ionic liquids as promoters and stabilising agents for the preparation of metal(0) nanoparticles by reduction and decomposition of organometallic complexes
AU - Prechtl, Martin H. G.
AU - Campbell, P. S.
AU - Scholten, J. D.
AU - Fraser, G. B.
AU - Machado, G.
AU - Santini, C. C.
AU - Dupont, J.
AU - Chauvin, Y.
N1 - ISI Document Delivery No.: 705UY Times Cited: 19 Cited Reference Count: 49 Cited References: Bini R, 2006, CHEM COMMUN, P897, DOI 10.1039/b514988f BOENNEMANN H, 2008, NANOPARTICLES CATALY BOENNEMANN H, 2008, NANOCLUSTERS CATALYS, P21 CAMPBELL PS, 2010, J CATAL, V257, P99 Campbell PS, 2010, PHYS CHEM CHEM PHYS, V12, P4217, DOI 10.1039/b925329g Cassol CC, 2006, ADV SYNTH CATAL, V348, P243, DOI 10.1002/adsc.200505295 Choi S, 2007, KOREAN J CHEM ENG, V24, P856, DOI 10.1007/s11814-007-0054-2 Chowdhury S, 2007, TETRAHEDRON, V63, P2363, DOI 10.1016/j.tet.2006.11.001 Clement ND, 2004, ANGEW CHEM INT EDIT, V43, P1277, DOI 10.1002/anie.200353409 Cordente N, 2003, J APPL PHYS, V94, P6358, DOI 10.1063/1.1621081 Cordente N, 2001, NANO LETT, V1, P565, DOI 10.1021/nl0100522 Crudden CM, 2004, COORDIN CHEM REV, V248, P2247, DOI 10.1016/j.ccr.2004.05.013 Cui YG, 2010, PHYS CHEM CHEM PHYS, V12, P1834, DOI 10.1039/b920025h Dupont J, 2010, CHEM SOC REV, V39, P1780, DOI 10.1039/b822551f Fei ZF, 2007, ORGANOMETALLICS, V26, P1588, DOI 10.1021/om060950e Flannigan DJ, 2005, J ORGANOMET CHEM, V690, P3513, DOI 10.1016/j.jorganchem.2005.04.024 Gao Y, 2008, EUR J INORG CHEM, P3769, DOI 10.1002/ejic.200800467 GENET JP, 1991, TETRAHEDRON-ASYMMETR, V2, P43, DOI 10.1016/S0957-4166(00)82155-2 Graham DC, 2007, DALTON T, P4650, DOI 10.1039/b709914b Grundemann S, 2001, CHEM COMMUN, P2274, DOI 10.1039/b107881j Gutel T, 2007, J MATER CHEM, V17, P3290, DOI 10.1039/b706139k Gutel T, 2009, J MATER CHEM, V19, P3624, DOI 10.1039/b821659b Hintermair U, 2008, J ORGANOMET CHEM, V693, P2407, DOI 10.1016/j.jorganchem.2008.04.017 Kim KS, 2006, J MATER CHEM, V16, P1315, DOI 10.1039/b601478j Lecocq V, 2007, OIL GAS SCI TECHNOL, V62, P761, DOI 10.2516/ogst:2007070 Magna L, 2003, ORGANOMETALLICS, V22, P4418, DOI 10.1021/om021057s McGuinness DS, 2002, ORGANOMETALLICS, V21, P175, DOI 10.1021/om010717a Migowski P, 2007, PHYS CHEM CHEM PHYS, V9, P4814, DOI 10.1039/b703979d Migowski P, 2007, CHEM-EUR J, V13, P32, DOI 10.1002/chem.200601438 Migowski P, 2007, J ELECTRON SPECTROSC, V156, P195, DOI 10.1016/j.elspec.2006.11.027 Migowski P, 2010, PHYS CHEM CHEM PHYS, V12, P6826, DOI 10.1039/b925834e Ott LS, 2006, INORG CHEM, V45, P8382, DOI 10.1021/ic060876s Ott LS, 2007, INORG CHEM, V46, P10335, DOI 10.1021/ic700976z Ott LS, 2005, J AM CHEM SOC, V127, P5758, DOI 10.1021/ja0423320 Oxley JD, 2003, J AM CHEM SOC, V125, P11138, DOI 10.1021/ja029830y Prechtl MHG, 2008, INORG CHEM, V47, P8995, DOI 10.1021/ic801014f Prechtl MHG, 2009, J MOL CATAL A-CHEM, V313, P74, DOI 10.1016/j.molcata.2009.08.004 Prechtl MHG, 2010, MOLECULES, V15, P3441, DOI 10.3390/molecules15053441 Redel E, 2008, INORG CHEM, V47, P14, DOI 10.1021/ic702071w Redel E, 2008, CHEM COMMUN, P1789, DOI 10.1039/b718055a Ryu HJ, 2008, ANGEW CHEM INT EDIT, V47, P7639, DOI 10.1002/anie.200802185 Scariot M, 2008, ANGEW CHEM INT EDIT, V47, P9075, DOI 10.1002/anie.200804200 Scholten J. D., 2009, IRIDIUM COMPLEXES OR, P369 Scholten JD, 2007, DALTON T, P5554, DOI 10.1039/b707888a Scholten JD, 2008, ORGANOMETALLICS, V27, P4439, DOI 10.1021/om8003948 Silva DO, 2008, CHEMSUSCHEM, V1, P291, DOI 10.1002/cssc.200800022 Silveira ET, 2004, CHEM-EUR J, V10, P3734, DOI 10.1002/chem.200305765 Sowmiah S, 2009, MOLECULES, V14, P3780, DOI 10.3390/molecules14093780 Zhao L, 2008, J AM CHEM SOC, V130, P12586, DOI 10.1021/ja8037883 Prechtl, Martin H. G. Campbell, Paul S. Scholten, Jackson D. Fraser, Georgina B. Machado, Giovanna Santini, Catherine C. Dupont, Jairton Chauvin, Yves Dupont, Jairton/F-7161-2010; Prechtl, Martin/A-7416-2008 Prechtl, Martin/0000-0003-2155-8006 ANR [ANR-07-CP2D-02-03]; Ministere de l'enseignement superieur et de la recherche; CNPq; CAPES; INCT-Catal; Alexander-von-Humboldt Foundation; Erasmus programme This work was funded by ANR project CALIST (ANR-07-CP2D-02-03), the "Ministere de l'enseignement superieur et de la recherche" (P.S.C.), CNPq, CAPES, INCT-Catal. and the Alexander-von-Humboldt Foundation (M. H. G. Prechtl). G.B.F. acknowledges the grant attributed by the Erasmus programme. 19 Royal soc chemistry Cambridge
PY - 2010
Y1 - 2010
N2 - The organometallic complexes ([Ru(COD)(2-methylallyl)(2)] and [Ni(COD)(2)] (COD = 1,5-cyclooctadiene) dissolved in imidazolium ionic liquids (ILs) undergo reduction and decomposition, respectively, to afford stable ruthenium and nickel metal(0) nanoparticles (Ru(0)-NPs and Ni(0)-NPs) in the absence of classical reducing agents. Depending on the case, the reduction/auto-decomposition is promoted by either the cation and/or anion of the neat imidazolium ILs.
AB - The organometallic complexes ([Ru(COD)(2-methylallyl)(2)] and [Ni(COD)(2)] (COD = 1,5-cyclooctadiene) dissolved in imidazolium ionic liquids (ILs) undergo reduction and decomposition, respectively, to afford stable ruthenium and nickel metal(0) nanoparticles (Ru(0)-NPs and Ni(0)-NPs) in the absence of classical reducing agents. Depending on the case, the reduction/auto-decomposition is promoted by either the cation and/or anion of the neat imidazolium ILs.
KW - heterocyclic carbene complexes size-dependent formation nickel nanoparticles ruthenium catalysts oxidative addition coupling reactions rhodium complexes hydrogenation salts anion Chemistry Science & Technology - Other Topics Materials Science Physics
U2 - 10.1039/c0nr00574f
DO - 10.1039/c0nr00574f
M3 - Journal article
VL - 2
SP - 2601
EP - 2606
JO - Nanoscale
JF - Nanoscale
SN - 2040-3364
IS - 12
ER -