Hydrogen storage in amine boranes: Ionic liquid supported thermal dehydrogenation of ethylene diamine bisborane

Sebastian Sahler, Hannelore Konnerth, Nicole Knoblauch, M. H. G. Prechtl

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

Abstract

A variety of ionic liquids has been tested for its catalytic effect on the dehydrogenation of ethylene diamine bisborane (EDB). The catalytic activity of ionic liquids, such as 1-butyl-2,3-dimethylimidazolium chloride ([BMMIM]Cl), 1-butyl-2,3-dimethylimidazolium acetate ([BMMIM][OAc]), 1-butyl-3-methylimidazolium acetate ([BMIM][OAc]) and 1-butyl-3-methylimidazolium methylsulfonate ([BMIM][OMs]) is compared and the mixture [BMMIM]Cl/EDB was investigated. This system is able to deliver about 6.5 wt% of hydrogen at 140 degrees C competing with conventional hydrogen storage pressure tanks. The correlation between polarity of the ILs and hydrogen yield was investigated and the suitability for hydrogen storage systems is evaluated and discussed. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
OriginalsprogEngelsk
TidsskriftInternational Journal of Hydrogen Energy
Vol/bind38
Udgave nummer8
Sider (fra-til)3283-3290
Antal sider8
ISSN0360-3199
DOI
StatusUdgivet - 2013
Udgivet eksterntJa

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