Fridel-Crafts acylation using bismuth triflate in [BMI][PF6]

Phuong Hoang Tran; Fritz Duus; Thach Ngoc Le

doi:10.1016/j.tetlet.2011.11.022

Fridel-Crafts acylation using bismuth triflate in [BMI][PF₆]

Phuong Hoang Tran
, Fritz Duus
, Thach Ngoc Le

Kemi

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

40 Citationer (Scopus)

Abstract

Bismuth trifluoromethanesulfonate was found to be a good catalyst for the Friedel–Craftsacylation. Bismuthtriflate immobilized in an ionic liquid was the most efficient catalytic system. Bismuthtriflate in [BMI][PF6] catalyzes this reaction under microwave irradiation allowing the rapid synthesis of aryl ketones in excellent yields. The catalyst system was easily recovered and reused several times.

Originalsprog	Engelsk
Tidsskrift	Tetrahedron Letters
Vol/bind	53
Udgave nummer	2
Sider (fra-til)	222-224
Antal sider	3
ISSN	0040-4039
DOI	https://doi.org/10.1016/j.tetlet.2011.11.022
Status	Udgivet - 2012

Adgang til dokumentet

10.1016/j.tetlet.2011.11.022

Citationsformater

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title = "Fridel-Crafts acylation using bismuth triflate in [BMI][PF6]",

abstract = "Bismuth trifluoromethanesulfonate was found to be a good catalyst for the Friedel–Craftsacylation. Bismuthtriflate immobilized in an ionic liquid was the most efficient catalytic system. Bismuthtriflate in [BMI][PF6] catalyzes this reaction under microwave irradiation allowing the rapid synthesis of aryl ketones in excellent yields. The catalyst system was easily recovered and reused several times.",

keywords = "Bismuthtriflate, Ionic liquid, Microwave, Friedel–Craftsacylation",

author = "Tran, \{Phuong Hoang\} and Fritz Duus and Le, \{Thach Ngoc\}",

year = "2012",

doi = "10.1016/j.tetlet.2011.11.022",

language = "English",

volume = "53",

pages = "222--224",

journal = "Tetrahedron Letters",

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TY - JOUR

T1 - Fridel-Crafts acylation using bismuth triflate in [BMI][PF6]

AU - Tran, Phuong Hoang

AU - Duus, Fritz

AU - Le, Thach Ngoc

PY - 2012

Y1 - 2012

N2 - Bismuth trifluoromethanesulfonate was found to be a good catalyst for the Friedel–Craftsacylation. Bismuthtriflate immobilized in an ionic liquid was the most efficient catalytic system. Bismuthtriflate in [BMI][PF6] catalyzes this reaction under microwave irradiation allowing the rapid synthesis of aryl ketones in excellent yields. The catalyst system was easily recovered and reused several times.

AB - Bismuth trifluoromethanesulfonate was found to be a good catalyst for the Friedel–Craftsacylation. Bismuthtriflate immobilized in an ionic liquid was the most efficient catalytic system. Bismuthtriflate in [BMI][PF6] catalyzes this reaction under microwave irradiation allowing the rapid synthesis of aryl ketones in excellent yields. The catalyst system was easily recovered and reused several times.

KW - Bismuthtriflate

KW - Ionic liquid

KW - Microwave

KW - Friedel–Craftsacylation

U2 - 10.1016/j.tetlet.2011.11.022

DO - 10.1016/j.tetlet.2011.11.022

M3 - Journal article

SN - 0040-4039

VL - 53

SP - 222

EP - 224

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 2

ER -