Efficient Friedel-Crafts benzoylation of aniline derivatives with 4-fluorobenzoyl chloride using copper triflate in the synthesis of aminobenzophenones

Phuong Hoang Tran; Huy Quang Phung; Poul Erik Hansen; Hai Ngoc Tran; Thach Ngoc Le

doi:10.1080/00397911.2016.1148164

Efficient Friedel-Crafts benzoylation of aniline derivatives with 4-fluorobenzoyl chloride using copper triflate in the synthesis of aminobenzophenones

Phuong Hoang Tran, Huy Quang Phung, Poul Erik Hansen, Hai Ngoc Tran, Thach Ngoc Le

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Abstract

An efficient pathway for the synthesis of the aminobenzophenone
derivatives via Friedel–Crafts benzoylation using copper triflate as
catalyst is proposed. New derivatives are synthesized. The copper
triflate could be easily recovered and reused without loss of catalytic
activity. Both the use of ionic liquids and microwave heating turned
out to be fruitful.

Originalsprog	Engelsk
Tidsskrift	Synthetic Communications
Vol/bind	46
Udgave nummer	10
Sider (fra-til)	893-901
Antal sider	9
ISSN	0039-7911
DOI	https://doi.org/10.1080/00397911.2016.1148164
Status	Udgivet - 2016

Bibliografisk note

Imortant note from the Publisher regarding the attached document:
“This is an Accepted Manuscript of an article published by Taylor & Francis in Synthetic Communication on 03 Jun 2016, available online: http://www.tandfonline.com/10.1080/00397911.2016.1148164.”

Emneord

Friedel-Crafts acylation
microwave

Link til dokument

10.1080/00397911.2016.1148164

SyntcommTranpehfin-accepted manuscriptAccepteret manuskript, 72,9 KB

Citer dette

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abstract = "An efficient pathway for the synthesis of the aminobenzophenonederivatives via Friedel–Crafts benzoylation using copper triflate ascatalyst is proposed. New derivatives are synthesized. The coppertriflate could be easily recovered and reused without loss of catalyticactivity. Both the use of ionic liquids and microwave heating turnedout to be fruitful.",

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AU - Hansen, Poul Erik

AU - Tran, Hai Ngoc

AU - Le, Thach Ngoc

N1 - Imortant note from the Publisher regarding the attached document: “This is an Accepted Manuscript of an article published by Taylor & Francis in Synthetic Communication on 03 Jun 2016, available online: http://www.tandfonline.com/10.1080/00397911.2016.1148164.”

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AB - An efficient pathway for the synthesis of the aminobenzophenonederivatives via Friedel–Crafts benzoylation using copper triflate ascatalyst is proposed. New derivatives are synthesized. The coppertriflate could be easily recovered and reused without loss of catalyticactivity. Both the use of ionic liquids and microwave heating turnedout to be fruitful.

KW - Friedel-Crafts acylation

KW - microwave

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DO - 10.1080/00397911.2016.1148164

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