Efficient Friedel-Crafts benzoylation of aniline derivatives with 4-fluorobenzoyl chloride using copper triflate in the synthesis of aminobenzophenones

Phuong Hoang Tran, Huy Quang Phung, Poul Erik Hansen, Hai Ngoc Tran, Thach Ngoc Le

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

Resumé

An efficient pathway for the synthesis of the aminobenzophenone
derivatives via Friedel–Crafts benzoylation using copper triflate as
catalyst is proposed. New derivatives are synthesized. The copper
triflate could be easily recovered and reused without loss of catalytic
activity. Both the use of ionic liquids and microwave heating turned
out to be fruitful.
OriginalsprogEngelsk
TidsskriftSynthetic Communications
Vol/bind46
Udgave nummer10
ISSN0039-7911
DOI
StatusUdgivet - 2016

Bibliografisk note

Imortant note from the Publisher regarding the attached document:
“This is an Accepted Manuscript of an article published by Taylor & Francis in Synthetic Communication on 03 Jun 2016, available online: http://www.tandfonline.com/10.1080/00397911.2016.1148164.”

Emneord

  • Friedel-Crafts acylation
  • microwave

Citer dette

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title = "Efficient Friedel-Crafts benzoylation of aniline derivatives with 4-fluorobenzoyl chloride using copper triflate in the synthesis of aminobenzophenones",
abstract = "An efficient pathway for the synthesis of the aminobenzophenonederivatives via Friedel–Crafts benzoylation using copper triflate ascatalyst is proposed. New derivatives are synthesized. The coppertriflate could be easily recovered and reused without loss of catalyticactivity. Both the use of ionic liquids and microwave heating turnedout to be fruitful.",
keywords = "Friedel-Crafts acylation, microwave",
author = "Tran, {Phuong Hoang} and Phung, {Huy Quang} and Hansen, {Poul Erik} and Tran, {Hai Ngoc} and Le, {Thach Ngoc}",
note = "Imortant note from the Publisher regarding the attached document: “This is an Accepted Manuscript of an article published by Taylor & Francis in Synthetic Communication on 03 Jun 2016, available online: http://www.tandfonline.com/10.1080/00397911.2016.1148164.”",
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Efficient Friedel-Crafts benzoylation of aniline derivatives with 4-fluorobenzoyl chloride using copper triflate in the synthesis of aminobenzophenones. / Tran, Phuong Hoang; Phung, Huy Quang; Hansen, Poul Erik; Tran, Hai Ngoc; Le, Thach Ngoc.

I: Synthetic Communications, Bind 46, Nr. 10, 2016.

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

TY - JOUR

T1 - Efficient Friedel-Crafts benzoylation of aniline derivatives with 4-fluorobenzoyl chloride using copper triflate in the synthesis of aminobenzophenones

AU - Tran, Phuong Hoang

AU - Phung, Huy Quang

AU - Hansen, Poul Erik

AU - Tran, Hai Ngoc

AU - Le, Thach Ngoc

N1 - Imortant note from the Publisher regarding the attached document: “This is an Accepted Manuscript of an article published by Taylor & Francis in Synthetic Communication on 03 Jun 2016, available online: http://www.tandfonline.com/10.1080/00397911.2016.1148164.”

PY - 2016

Y1 - 2016

N2 - An efficient pathway for the synthesis of the aminobenzophenonederivatives via Friedel–Crafts benzoylation using copper triflate ascatalyst is proposed. New derivatives are synthesized. The coppertriflate could be easily recovered and reused without loss of catalyticactivity. Both the use of ionic liquids and microwave heating turnedout to be fruitful.

AB - An efficient pathway for the synthesis of the aminobenzophenonederivatives via Friedel–Crafts benzoylation using copper triflate ascatalyst is proposed. New derivatives are synthesized. The coppertriflate could be easily recovered and reused without loss of catalyticactivity. Both the use of ionic liquids and microwave heating turnedout to be fruitful.

KW - Friedel-Crafts acylation

KW - microwave

U2 - 10.1080/00397911.2016.1148164

DO - 10.1080/00397911.2016.1148164

M3 - Journal article

VL - 46

JO - Synthetic Communications

JF - Synthetic Communications

SN - 0039-7911

IS - 10

ER -