Communication: High pressure specific heat spectroscopy reveals simple relaxation behavior of glass forming molecular liquid

Lisa Anita Roed, Kristine Niss, Bo Jakobsen

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The frequency dependent specific heat has been measured under pressure for the molecular glass forming liquid 5-polyphenyl-4-ether in the viscous regime close to the glass transition. The temperature and pressure dependences of the characteristic time scale associated with the specific heat is compared to the equivalent time scale from dielectric spectroscopy performed under identical conditions. It is shown that the ratio between the two time scales is independent of both temperature and pressure. This observation is non-trivial and demonstrates the existence of specially simple molecular liquids in which different physical relaxation processes are both as function of temperature and pressure/density governed by the same underlying “inner clock.” Furthermore, the results are discussed in terms of the recent conjecture that van der Waals liquids, like the measuredliquid, comply to the isomorph theory
TidsskriftJournal of Chemical Physics
StatusUdgivet - 9 dec. 2015

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