Abstract
This paper presents accurate data for the physical aging of organic glasses just below the glass transition probed by monitoring the following quantities after temperature up and down jumps: the shear-mechanical resonance frequency (∼360 kHz), the dielectric loss at 1 Hz, the real part of the dielectric constant at 10 kHz, and the loss-peak frequency of the dielectric beta process (∼10 kHz). The setup used allows for keeping temperature constant within 100 μK and for thermal equilibration within a few seconds after a temperature jump. The data conform to a new simplified version of the classical Tool-Narayanaswamy aging formalism, which makes it possible to calculate one relaxation curve directly from another without any fitting to analytical functions.
Originalsprog | Engelsk |
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Artikelnummer | 241103 |
Tidsskrift | Journal of Chemical Physics |
Vol/bind | 142 |
ISSN | 0021-9606 |
DOI | |
Status | Udgivet - 2015 |