An efficient and green synthesis of 1-indanone and 1-tetralone via intramolecular Friedel-Crafts acylation reaction

Phuong Hoang Tran; Vy Hieu Huynh; Poul Erik Hansen; Duy-Khiem Nguyen Chau; Thach Ngoc Le

doi:10.1002/ajoc.201402274

An efficient and green synthesis of 1-indanone and 1-tetralone via intramolecular Friedel-Crafts acylation reaction

Phuong Hoang Tran, Vy Hieu Huynh, Poul Erik Hansen, Duy-Khiem Nguyen Chau, Thach Ngoc Le

Kemi

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Abstract

Metal-triflate-catalyzed intramolecular Friedel–Crafts acylation of 3-arylpropanoic and 4-arylbutanoic acids in triflate-anion ionic liquids under monomodal microwave irradiation is reported. The environmentally benign synthetic procedure allows the formation of cyclic ketones in good yields within a short reaction time. The catalytic metal triflate in triflate-anion ionic liquids can be easily recovered and reused several times without significant loss of the catalytic performance.

Originalsprog	Engelsk
Tidsskrift	Asian Journal of Organic Chemistry
Vol/bind	4
Udgave nummer	5
Sider (fra-til)	482-86.
Antal sider	5
ISSN	2193-5807
DOI	https://doi.org/10.1002/ajoc.201402274
Status	Udgivet - 2015

Emneord

Friedel-Crafts
Cyclisation
metal triflate
Ionic liquid
indanone
tetralone

Link til dokument

10.1002/ajoc.201402274

Citer dette

Tran, P. H., Huynh, V. H., Hansen, P. E., Chau, D-K. N., & Le, T. N. (2015). An efficient and green synthesis of 1-indanone and 1-tetralone via intramolecular Friedel-Crafts acylation reaction. Asian Journal of Organic Chemistry, 4(5), 482-86.. https://doi.org/10.1002/ajoc.201402274

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title = "An efficient and green synthesis of 1-indanone and 1-tetralone via intramolecular Friedel-Crafts acylation reaction",

abstract = "Metal-triflate-catalyzed intramolecular Friedel–Crafts acylation of 3-arylpropanoic and 4-arylbutanoic acids in triflate-anion ionic liquids under monomodal microwave irradiation is reported. The environmentally benign synthetic procedure allows the formation of cyclic ketones in good yields within a short reaction time. The catalytic metal triflate in triflate-anion ionic liquids can be easily recovered and reused several times without significant loss of the catalytic performance.",

keywords = "Friedel-Crafts, Cyclisation, metal triflate, Ionic liquid, indanone, tetralone, Friedel-Crafts, Cyclysation, Microwave, green chemistry, indanone, ionic liquid, terbium triflate",

author = "Tran, {Phuong Hoang} and Huynh, {Vy Hieu} and Hansen, {Poul Erik} and Chau, {Duy-Khiem Nguyen} and Le, {Thach Ngoc}",

year = "2015",

doi = "10.1002/ajoc.201402274",

language = "English",

volume = "4",

pages = "482--86.",

journal = "Asian Journal of Organic Chemistry",

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publisher = "Wiley - V C H Verlag GmbH & Co. KGaA",

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An efficient and green synthesis of 1-indanone and 1-tetralone via intramolecular Friedel-Crafts acylation reaction. / Tran, Phuong Hoang; Huynh, Vy Hieu; Hansen, Poul Erik; Chau, Duy-Khiem Nguyen; Le, Thach Ngoc.

I: Asian Journal of Organic Chemistry, Bind 4, Nr. 5, 2015, s. 482-86.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

TY - JOUR

T1 - An efficient and green synthesis of 1-indanone and 1-tetralone via intramolecular Friedel-Crafts acylation reaction

AU - Tran, Phuong Hoang

AU - Huynh, Vy Hieu

AU - Hansen, Poul Erik

AU - Chau, Duy-Khiem Nguyen

AU - Le, Thach Ngoc

PY - 2015

Y1 - 2015

N2 - Metal-triflate-catalyzed intramolecular Friedel–Crafts acylation of 3-arylpropanoic and 4-arylbutanoic acids in triflate-anion ionic liquids under monomodal microwave irradiation is reported. The environmentally benign synthetic procedure allows the formation of cyclic ketones in good yields within a short reaction time. The catalytic metal triflate in triflate-anion ionic liquids can be easily recovered and reused several times without significant loss of the catalytic performance.

AB - Metal-triflate-catalyzed intramolecular Friedel–Crafts acylation of 3-arylpropanoic and 4-arylbutanoic acids in triflate-anion ionic liquids under monomodal microwave irradiation is reported. The environmentally benign synthetic procedure allows the formation of cyclic ketones in good yields within a short reaction time. The catalytic metal triflate in triflate-anion ionic liquids can be easily recovered and reused several times without significant loss of the catalytic performance.

KW - Friedel-Crafts

KW - Cyclisation

KW - metal triflate

KW - Ionic liquid

KW - indanone

KW - tetralone

KW - Friedel-Crafts

KW - Cyclysation

KW - Microwave

KW - green chemistry

KW - indanone

KW - ionic liquid

KW - terbium triflate

U2 - 10.1002/ajoc.201402274

DO - 10.1002/ajoc.201402274

M3 - Journal article

VL - 4

SP - 482-86.

JO - Asian Journal of Organic Chemistry

JF - Asian Journal of Organic Chemistry

SN - 2193-5807

IS - 5

ER -