Abstract
Dielectric measurements on molecular liquids just above the glass transition indicate that alpha relaxation is characterized by a generic high-frequency loss varying as one over square root of frequency, whereas deviations from this come from one or more low-lying beta processes [Olsen et al., Phys. Rev. Lett., 86 (2001) 1271]. Assuming that long-wavelength fluctuations dominate the dynamics, a model for the dielectric alpha relaxation based on the simplest coupling between the density and dipole density fields is proposed here. The model, which is solved in second-order perturbation theory in the Gaussian approximation, reproduces the generic features of alpha relaxation.
| Originalsprog | Udefineret/Ukendt |
|---|---|
| Tidsskrift | EPL |
| Vol/bind | 71 |
| Udgave nummer | 4 |
| Sider (fra-til) | 646-650 |
| ISSN | 0295-5075 |
| DOI | |
| Status | Udgivet - 2005 |