40Ar/39Ar dating of Quaternary volcanic ashes by multi-collection noble gas mass spectrometry: protocols, precision and intercalibration

Michael Storey, Tiffany Rivera, Stephanie Flude, Ole Stecher

    Publikation: KonferencebidragKonferenceabstrakt til konferenceForskning


    The recent availability of commercial high-resolution, multi-collector, noble gas mass spectrometers equipped with ion-counting electron multipliers provides new opportunities for improved precision in 40Ar/39Ar dating. This is particularly true for single crystal dating of Quaternary aged samples where potassium-bearing phenocrysts may contain relatively small amounts of radiogenic 40Ar.

    In 2005, the Quaternary Dating Laboratory, Roskilde University, installed a Nu-Instruments multi-collector Noblesse noble gas mass spectrometer, which is configured with a Faraday detector and three ion-counting electron multipliers. The instrument has the capability to measure several isotopes simultaneously and to change measurement configurations instantaneously by the use of QUAD lenses (zoom optics). The Noblesse offers several advantages over previous generation instruments and is particularly suited for single crystal 40Ar/39Ar dating of Quaternary samples because of: (i) improved source sensitivity; (ii) ion-counting electron multipliers, which have low signal to noise ratios enabling precise measurement of very small 36Ar signals - resulting in accurate correction for atmospheric-derived 40Ar; (iii) higher mass resolution allows hydrocarbon interferences to be pseudo resolved for the different argon isotopes; and (iv) multi-collection, allowing more data to be gathered in a fixed time in comparison with single-collector peak-switching measurements.

    We evaluate (i) protocols for detector inter-calibration and instrument mass fractionation using argon from a calibrated air pipette; (ii) precision and long-term data reproducibility; and (iii) results from inter-calibration experiments of 40Ar/39Ar ages on Quaternary volcanic ashes with the U-Pb, astronomical and historical chronometers.
    Publikationsdatojul. 2011
    StatusUdgivet - jul. 2011
    BegivenhedXVIII INQUA Congress - Quaternary sciences – the view from the mountains - Bern, Schweiz
    Varighed: 21 jul. 201127 jul. 2011
    Konferencens nummer: 18


    KonferenceXVIII INQUA Congress - Quaternary sciences – the view from the mountains

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